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The in-vitro proliferation-suppression of MCF-7 and HeLa cell lines mediated by differently substituted ionic phthalocyanines in sonodynamic therapy supplemented-photodynamic therapy

- Nene, Lindokuhle Cindy, Nyokong, Tebello

  • Authors: Nene, Lindokuhle Cindy , Nyokong, Tebello
  • Date: 2023
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/360461 , vital:65090 , xlink:href="https://doi.org/10.1016/j.jinorgbio.2022.112084"
  • Description: This work focuses on the study of the effects of the ultrasonic frequency (MHz) and power (W.cm−2) on the stability, reactive oxygen species yields and cytotoxicity activities of differently substituted ionic phthalocyanines (Pcs) in sonodynamic therapy (SDT). Four ultrasonic parameters were investigated: Par I (1 MHz: 1 W.cm−2), Par II (1 MHz: 2 W.cm−2), Par III (3 MHz: 1 W.cm−2) and Par IV (3 MHz: 2 W.cm−2). A higher degradation of the Pcs was observed with increasing power at the Par II. Two reactive oxygen species (ROS) were detected in the ultrasound treated Pcs: singlet oxygen and hydroxyl radicals. Due to minimal degradation of most Pcs, Par I was chosen for SDT, photodynamic therapy (PDT), and photo-sonodynamic therapy (PSDT) against Michigan Cancer Foundation-7 and Henrietta Lacks cancer cell lines. PSDT generally showed improved therapeutic efficacies of the Pcs compared to the SDT and PDT mono treatments.
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  • Date Issued: 2023

The nature of competition in the banking sector and its effect on financial inclusion in South Africa

- Ngonyama, Nomasomi https://orcid.org/0000-0002-7536-9297

  • Authors: Ngonyama, Nomasomi https://orcid.org/0000-0002-7536-9297
  • Date: 2023
  • Subjects: Banks and banking -- South Africa , Competition -- South Africa , Financial services industry
  • Language: English
  • Type: Doctoral theses , text
  • Identifier: http://hdl.handle.net/10353/28661 , vital:74492
  • Description: Competition and access to financial services are lauded as key ingredients in the fight against poverty. While competition enhances markets, fosters innovation, productivity and growth, financial inclusion allows the poor to save, access credit and insurance thereby allowing them to meaningfully contribute to economic growth and also smooth their consumption. Moreover, competition reduces the cost of finance, thereby further expanding the availability of financial services. This suggests an important relationship between competition in the banking sector and financial inclusion. Research in this area is still in its infancy and little consensus exists on both whether the relationship is a robust one or not. There is no unanimity on the direction of causality or whether competition in the financial sector is good or bad for markets. This study examines the nexus between banking competition and financial inclusion in Upper-middle income countries. It employed a panel data set over the period 2011-2017 and Generalized Methods of Moments technique was employed to answer this enquiry. The findings of this study suggest that market power is not bad for financial inclusion in upper-middle income countries. Moreover, the study found that bank competition does not matter in banking the unbanked population in Upper-middle income countries. The implication of the findings of this study is that the focus of the policy makers should not be on policies that reduces concentration and market power in the banking sector, but be on measures that encourages contestability. The threat of entry is sufficient to make banks behave in a competitive manner. , Thesis (PhD) -- Faculty of Management and Commerce, 2023
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  • Date Issued: 2023

The prevalence, uses and cultural assimilation of shrub and tree invasive alien plants in a biodiversity hotspot along the Wild Coast, South Africa

- Wootton, Oscar, Shackleton, Charlie M

  • Authors: Wootton, Oscar , Shackleton, Charlie M
  • Date: 2023
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/401314 , vital:69725 , xlink:href="https://doi.org/10.1080/26395916.2023.2216804"
  • Description: Invasive alien plant species (IAPS) frequently offer both ecosystem services and disservices to rural communities with high livelihood dependency on local landscapes. However, biocultural relationships with IAPS may go deeper than just provisioning uses, as they may be assimilated into local belief systems manifest in them becoming embedded in cultural constructions such as naming, stories, songs and ceremonies. It is likely that IAPS that are culturally assimilated will represent a greater conflict of interest in the face of proposed controls of IAPS in biodiversity hotspots where conservation priorities are frequently deemed paramount by external agencies. Using a mixed-methods approach we undertook roadside surveys of 17 selected IAPS along the 250 km Wild Coast section of the Maputaland-Pondoland-Albany biodiversity hotspot, accompanied by questionnaire interviews with 48 local people. The mean number of IAPS per site was four, ranging from zero (only one site) to ten, and local inhabitants deemed the abundance of all but one of the species to be increasing. All species had been in the region for decades, had a vernacular name, and all but one had direct consumptive uses. Species with multiple uses were more widely recognised. However, there was only marginal incorporation of the IAPS into stories, songs and ceremonies, although medicinal uses of some IAPS were for cultural/spiritual needs rather than physical ailments per se. These results show that despite widespread use, there was as yet relatively limited cultural assimilation of the IAPS in the Wild Coast region.
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  • Date Issued: 2023

The Role of the University as Mediator in a Skills Ecosystem Approach to VET

- Lotz-Sisitka, Heila, Openjuru, George, Zeelen, Jacques

  • Authors: Lotz-Sisitka, Heila , Openjuru, George , Zeelen, Jacques
  • Date: 2023
  • Subjects: To be catalogued
  • Language: English
  • Type: text , book chapter
  • Identifier: http://hdl.handle.net/10962/434907 , vital:73115 , ISBN 978-1529224634 , https://bristoluniversitypress.co.uk/transitioning-vocational-education-and-training-in-africa
  • Description: In this chapter, we focus particularly on the mediating role of the university, in close connection with vocational institutions and informal community actors, in developing an inclusive approach to vocational education and training (VET) through an expanded social ecosystem for skills model. Here we draw upon lessons learnt from the Alice and Gulu cases on communitybased approaches to establishing an expanded skills ecosystem approach to VET in Africa. The main ques-tion guiding this chapter relates to the possible mediating role of the university to enhance a regional expanded ecosystem for supporting quality vocational education that is also rele-vant to its context, including emergent possibilities to build skills and livelihoods linked to just transitions. Universities are not VET centres as conventionally understood, but they can contribute to VET in various ways. Most often, universities are identified as contributing to the qualifications and training of VET educators. In this chapter, we take a different angle and consider the role of engaged research and community engagement as two approaches that can contribute to the advancement of an expanded social ecosystem model with positive benefits for VET institutions. Drawing on insights gained in the earlier chapters of this book requires us to take into account several important realities as previously dis-cussed, as well as key ingredients for the development of a regional skills ecosystem of vocational education, as demon-strated by the two cases considered in this chapter.
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  • Date Issued: 2023

The Southern African Program on Ecosystem Change and Society: an emergent community of practice

- Biggs, Reinette, Reyers, Belinda, Blanchard, Ryan, Clements, Hayley S, Cockburn, Jessica J, Cumming, Graeme S, Cundill, Georgina, de Vos, Alta, Dziba, Luthando E, Esler, Karen J, Fabricius, Christo, Hamann, Maike, Henriksson, Rebecka, Kotschy, Karen, Lindborg, Regina, Luvuno, Linda, Masterson, Vanessa A, Nel, Jeanne L, O'Farrell, Patrick, Palmer, Carolyn G, Pereira, Laura, Pollard, Sharon, Preiser, Rika, Roux, Dirk J, Scholes, Robert J, Selomane, Odirlwe, Shackleton, Charlie M, Shackleton, Sheona E, Sitas, Nadia, Slingsby, Jasper A, Spierenburg, Marja, Tengö, Maria

The Training of pre-service science teachers in the integration of Information and Communication Technology integration in Science teaching: A case of two colleges of education in The Volta Region of Ghana

- Ofori, Mac-Jones

  • Authors: Ofori, Mac-Jones
  • Date: 2023
  • Subjects: Teachers -- Training of , Science -- Study and teaching , Information technology -- Study and teaching
  • Language: English
  • Type: Doctoral theses , text
  • Identifier: http://hdl.handle.net/10353/27898 , vital:70467
  • Description: The study was carried out to investigate the training of pre-service Science teachers in the integration of Information and Communication Technology (ICT) in Science teaching at two colleges of education in the Volta region of Ghana. The study aimed to recommend a framework that can be used to enhance the training in ICT integration competencies of pre-service Science teachers at colleges of education in the country. The study was underpinned by two theoretical frameworks: Rogan and Grayson’s curriculum implementation framework and Guzman and Nussbaum’s ICT integration framework and was located within the interpretive paradigm. The qualitative research approach was adopted to generate data on the types of ICT integration competences that pre-service Science teachers are trained in, the pedagogical strategies used, the support provided, and the challenges faced during the training. The study adopted the explanatory case study design. Convenience and purposive sampling were used to select the study sites and participants respectively, which consisted of two teacher education colleges, two heads of Science department, ten lecturers, and 20 pre-service Science teachers. The study’s data collection methods were semi-structured face-to-face interviews with the lecturers, focus group discussions with the pre-service Science teachers, non-participatory lesson observation, and document analysis. The data was analysed using thematic approach. The study established that pre-service Science teachers at the two colleges received training in mastering the usage of ICT tools, relating ICT to teaching; using ICT for assessment and providing feedback, creating an appropriate environment for ICT integration, and developing positive attitudes toward ICT usage. The study revealed the pedagogical strategies used for training the pre-service Science teachers in ICT integration competencies to include a standalone ICT course, demonstration, group work, self-learning and how assessment is carried out. The study also established that there was support from both within and without the college environment in training pre-service Science teachers, although this was inadequate. The major challenges found by the study to be hindering effective pre-service teacher training in ICT integration competencies were lack of technical know-how among lecturers, poor pre-service Science teachers’ backgrounds in ICT, inadequate ICT resources and infrastructure, prolonged organisational and management bureaucracy, and insufficient funding of ICT. The recommendations made included the need for upgrading infrastructure in the colleges while also upgrading lecturers’ competencies in handling ICT in the colleges. An alternative training framework for preparing pre-service Science teachers in ICT integration competencies was also proposed. , Thesis (MEd) -- Faculty of Education, 2023
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  • Date Issued: 2023

The trophic position and isotopic niche of a cryptogenic tube-building polychaete in a protected clear-water estuarine bay

- van Rensburg, Hendre, Richoux, Nicole B, Simon, Carol A

  • Authors: van Rensburg, Hendre , Richoux, Nicole B , Simon, Carol A
  • Date: 2023
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/454404 , vital:75341 , xlink:href="https://doi.org/10.1016/j.ecss.2023.108549"
  • Description: The Knysna Estuary is a large, clear-water embayment and one of the most important estuaries for conservation in southern Africa. The estuary is detritus-dominated and the benthic food webs have low diversities of carnivores, which may make the estuary vulnerable to invasions through the empty niche hypothesis. In the last two decades, the Knysna Estuary has experienced an increase in the population of the cryptogenic and apparently omnivorous estuarine moonshine worm (Diopatra aciculata). Our goal was to describe the trophic role of D. aciculata. We measured carbon and nitrogen stable isotopes in all the common macrophytes and macroinvertebrates across four seasons to 1) establish the isotopic landscapes of three disparate sites within the Knysna Estuary where D. aciculata occurs, 2) establish whether the trophic level of D. aciculata matches those of other common macroinvertebrates, and 3) establish whether the isotopic niche of D. aciculata overlaps with those of syntopic macroinvertebrates. Communities at the different sites differed in food web width, most likely due to differences in primary producer diversity. Our findings suggested that D. aciculata is a facultative carnivore, and some sub-populations are sustained primarily by animal tissues. Isotopic niche overlap analysis showed that direct competition with other common macroinvertebrate consumers is doubtful and D. aciculata occupies a unique niche within the estuary.
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  • Date Issued: 2023

The use of a Subjective wellbeing scale as predictor of adherence to neuroleptic treatment to determine poor prognostic factor in African population with Schizophrenia

- Boshe, J J, Stein, Dan J, Campbell, Megan M

  • Authors: Boshe, J J , Stein, Dan J , Campbell, Megan M
  • Date: 2023
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/450766 , vital:74980 , xlink:href="10.1192/j.eurpsy.2023.384"
  • Description: Objectives: To investigate and identify demographic and clinical predic-tors of subjective well-being in a sample of Xhosa people with schizo-phrenia on neuroleptic treatment. Methods: As a part of a large genetic study, 244 study participants with a confirmed diagnosis of schizophre-nia completed the translated SWN-K 20 scale. Internal consistency analysis was performed, and convergent analysis and exploratory analysis were conducted using Principal Component Analysis (PCA). Linear regression methods were used to determine predictors of SWBN in the sample population.
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  • Date Issued: 2023

Tragic Optimism: A Psychobiography of Morgan Richard Tsvangirai.

- Harry, Tinashe T, van Niekerk, Roelf

  • Authors: Harry, Tinashe T , van Niekerk, Roelf
  • Date: 2023
  • Subjects: To be catalogued
  • Language: English
  • Type: text , book chapter
  • Identifier: http://hdl.handle.net/10962/434439 , vital:73060 , ISBN 978-3-031-28826-5 , https://link.springer.com/chapter/10.1007/978-3-031-28827-2_5
  • Description: For many Zimbabweans, Morgan Richard Tsvangirai (1952–2018) became the face of courage and hope during his political career. Tsvangirai was subjected to and witnessed political violence, physical abuse, brutality, emotional humiliation, unlawful detentions, and persecution. He challenged the ruling party in Zimbabwe, and his leadership gave many people hope for the future. In the context of living in a colonial era, poverty, and having to endure the brutality of the Mugabe era, he lived a meaningful life that saw him becoming a Prime Minister of Zimbabwe (2009–2013). This single-case study explores and describes Tsvangirai’s life and interprets it in terms of Frankl’s existential theory. More specifically, Tsvangirai’s life is interpreted from the perspective of Frankl’s three triads, the fundamental, meaning, and tragic triads, as well as the noetic dimension. Tsvangirai was selected through purposive sampling based on his important role in Zimbabwean politics. The primary source of data was biographical and autobiographical publications. The findings indicate that Tsvangirai shifted emphasis within the meaning triad in living a meaningful life and that he was able to use the human capacity of self-distancing/detachment and self-transcendence to find meaning in his life. This chapter sheds light on how individuals make sense of their circumstances and search for meaning and purpose in adverse conditions. It also contributes towards the development of psychobiographical research among non-WEIRD samples.
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  • Date Issued: 2023

Transboundary Fisheries Management in Kavango–Zambezi Transfrontier Conservation Area (KAZA-TFCA): Prospects and Dilemmas

- Imbwae, Imikendu, Aswani, Shankar, Sauer, Warwick H H, Hay, Clinton J

  • Authors: Imbwae, Imikendu , Aswani, Shankar , Sauer, Warwick H H , Hay, Clinton J
  • Date: 2023
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/391433 , vital:68651 , xlink:href="https://doi.org/10.3390/su15054406"
  • Description: Inland fisheries in the Kavango–Zambezi Transfrontier Conservation Area (KAZA-TFCA) offer food security to the riverine communities across the region. They also contribute towards the attainment of the United Nations’ Sustainable Development Goals 1 and 15, which aim to alleviate poverty and maintain biodiversity conservation. Despite this significant role, the fisheries have suffered severe declines in the previous decades due to multiple factors, such as overfishing and poor legislation. Furthermore, climate change is exerting pressure by altering the ecology and productivity of the river systems. The unprecedented challenges of the COVID-19 pandemic have further constrained management efforts. Attempts to address these challenges have pointed towards transboundary fisheries management as a silver bullet in moving towards sustainable fisheries management. However, the implementation of this strategy in the region has encountered numerous roadblocks, thereby subjecting the river ecosystem to a wider environmental threat, with dire consequences on livelihoods. This paper reviews existing management and governance structures together with key informant interviews to elicit primary and secondary data essential for management at the regional level. The study identifies conflicting regulations, and inadequate policies and institutions across the region as major bottlenecks affecting the successful implementation of transboundary fisheries management. Finally, the paper offers some suggestions for the improvement of fisheries management in the region.
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  • Date Issued: 2023

Transnational Activities of Women-Focused Civil Society Actors in Southern Africa

- Nedziwe, Cecilia L, Tella, Oluwaseun

  • Authors: Nedziwe, Cecilia L , Tella, Oluwaseun
  • Date: 2023
  • Subjects: To be catalogued
  • Language: English
  • Type: text , book
  • Identifier: http://hdl.handle.net/10962/445327 , vital:74376 , ISBN 978-3-031-29536-2 , https://doi.org/10.1007/978-3-031-29537-9
  • Description: Since the 1990s, the opening up of democratic spaces has been characterised by growing transnational activities and regionalisation of non-state actors. In Southern Africa, intergovernmental organisations (IGOs) such as the Southern African Development Community (SADC) began to recognise civil society actors and to integrate and prioritise gender and women issues within their policymaking structures. 1 This was assisted by the formulation of norms at a global level which could be diffused to regional and national policies, leading to greater non-state activity in the SADC area. It was achieved through, firstly, the establishment of an eminent group of commissioners in the early 1990s to review the situation of women across the region. Secondly, following the 1995 Beijing International Women’s Conference, a task force was created to draft a Regional Plan of Action to begin to address gendered insecurities across Southern Africa. Finally, the first meeting of the SADC Ministers Responsible for Women and Gender Affairs was convened in 1997 (Made and Morna, 2009: 34).
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  • Date Issued: 2023

Trauma survivors’ perceptions and experiences of prolonged exposure for PTSD at a psychology clinic

- Booysen, Duane D, Kagee, Ashraf

  • Authors: Booysen, Duane D , Kagee, Ashraf
  • Date: 2023
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/454177 , vital:75316 , xlink:href="https://hdl.handle.net/10520/ejc-m_sajp_v29_n1_a1869"
  • Description: BACKGROUND Several trauma-focused treatments have been developed to treat post-traumatic stress disorder (PTSD). Yet there are limited studies on how trauma survivors perceive and experience trauma-focused treatments such as prolonged exposure therapy (PE) for PTSD, especially in low- and middle-income countries (LMIC). AIM The study aimed to explore the perceptions and experiences of trauma survivors receiving prolonged exposure therapy for PTSD and the general acceptability of PE for PTSD in a LMIC.
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  • Date Issued: 2023

TVET SI: Evaluating Boundary Crossing Social Learning in Vocational Education and Training: A value creation approach

- Lotz-Sisitka, Heila, Sisitka, Lawrence, Chakona, Gamuchirai, Matiwane, Mandilive L, Matambo, Chamu

  • Authors: Lotz-Sisitka, Heila , Sisitka, Lawrence , Chakona, Gamuchirai , Matiwane, Mandilive L , Matambo, Chamu
  • Date: 2023
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/389925 , vital:68495 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/238540"
  • Description: This article focuses on the development and application of an evaluation model and approach for evaluating boundary crossing social learning in a Vocational Education and Training (VET) learning network in South Africa, with an emphasis on a Training of Trainers (ToT) course that helped to catalyse and strengthen this learning network via two iterations of the course over an eight-year period. The article shares how we adapted the value creation framework (VCF) of Wenger, Traynor and De Laat (2011; Wenger and Wenger-Traynor, 2020) in the evaluation of a VET Training of Trainers (ToT) programme and learning network that focussed on the uptake and circulation of rainwater harvesting and conservation (RWHandC) knowledge in a particular formal and informal VET context in the Eastern Cape, South Africa, where smallholder farmers were struggling to find water for producing food. The evaluated ToT course was catalytic in establishing a boundary crossing social learning network approach in a VET context that linked formal and informal VET (Lotz-Sisitka et al., 2016; Lotz-Sisitka et al., 2022; Pesanayi, 2019); hence we found it important to develop adequate tools for its evaluation. The focus of this article is to share how we developed an evaluation approach to this work. We share insights on the indicators developed for diff erent types of value created, and also insights gained into the use of this evaluation approach in a boundary crossing VET social learning project that took a ToT course as focus. In short, evaluation findings show that the boundary crossing ToT course off ers strong immediate, potential and applied value that can lead to realised and reframed value, especially if supported by ongoing learning network activities that follow the initial engagement in the boundary crossing ToT course. Th is leads, over time, to transformative value which is important in achieving the overall objective of such social learning, namely making knowledge more co-engaging, accessible and useful in the context where improved food security via better use of rainwater harvesting and conservation amongst smallholder farmers and household food producers is a necessary form of sustainable development. Orientation value, and enabling value were found to be vital for the emergence of other kinds of value. The evaluation model also allows for the lifting out of strategic value which points to wider uptake potential. All this creates the possibility for indicator development that can help inform iterative development of boundary crossing VET courses used to stimulate the co-construction of learning networks and ongoing social learning for sustainable development.
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  • Date Issued: 2023

Two new Poyntonophrynus species (Anura: Bufonidae) highlight the importance of Angolan centers of endemism

- Baptista, Ninda L, Pinto, Pedro V, Keates, Chad, Lobón-Rovira, Javier, Edwards, Shelley, Rödel, Mark-Oliver

  • Authors: Baptista, Ninda L , Pinto, Pedro V , Keates, Chad , Lobón-Rovira, Javier , Edwards, Shelley , Rödel, Mark-Oliver
  • Date: 2023
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/461572 , vital:76214 , xlink:href="https://zoobank.org/7B5494CC-F8F2-46EA-BB73-D28B13D31CB6"
  • Description: The pygmy toad genus Poyntonophrynus is endemic to southern Africa. The morphology of these small toads is conserved. They are usually dully colored, and are predominately adapted to arid conditions. During recent surveys in Angola we found Poyntonophrynus specimens that were not assignable to known species. Using an integrative approach, based on mitochondrial and nuclear DNA, morphology, osteology, biogeography and ecology, we identified three new lineages, and describe two of them as new species. All three lineages are closely related to P. pachnodes, an Angolan endemic species, but they are geographically isolated from it. The new species are morphologically distinguishable, and are associated with two of the most important Angolan centers of endemism: the western escarpment and the central highlands. In order to get a more comprehensive understanding of the osteology of the genus, we also provide an osteological characterization of P. dombensis, which was not available to date. Our findings i) increase the number of earless species in the genus Poyntonophrynus, ii) emphasize southwestern Africa as the cradle of diversification in this genus, iii) report the occurrence of Poyntonophrynus in humid environments, thus showing that these toads are ecologically more variable than previously thought, and iv) underline the importance of further biodiversity studies in Angolan centers of endemism.
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  • Date Issued: 2023

Understanding foraging practices in Lagos metropolis to redesign urban greenspaces in support of human-nature interactions

- Adeyemi, Opeyemi, Shackleton, Charlie M

  • Authors: Adeyemi, Opeyemi , Shackleton, Charlie M
  • Date: 2023
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/401353 , vital:69728 , xlink:href="https://doi.org/10.1016/j.ufug.2022.127805"
  • Description: Enhancing knowledge of urban foraging across different urban landscapes is an urgent matter given that about two-thirds of the world’s population is projected to live in urban areas by 2050, whilst 50 % of Africa’s population is expected to live in cities by 2030. This study was conducted in Lagos metropolis which is the economic hub of Africa’s most populous country. Data was collected using an in-person, semi-structured questionnaire from 347 persons who were 18 years or older to identify foragers and non-foragers, their sociodemographic profiles, and their foraging practices. Results revealed that about two out of three persons sampled forage to some degree. The collection happened more in domestic gardens (34 %) and streets (27 %) than in other foraging sites (such as unused lands, institutional grounds and lakes and riparian fringes). A total of 35 species were reportedly foraged within the metropolis, mostly for food (71 %) and medicine (26 %). Mango (Mangifera indica), pawpaw (Carica papaya), tropical almond (Terminalia catappa), fish (various species), bitter leaf (Vernonia amygdalina) and spinach (Spinacia oleracea) were the most gathered species. The distance travelled to foraging wild species ranged from 5 m to 25 km. The primary motivation for foraging was the acquisition of fresh and natural materials. However, some felt that foraging was a stressful activity. The unavailability of foraging sites and species was the major constraint to foraging in this megacity. Hence, efforts to increase the edible components of public green spaces and to provide free access could potentially allow more people to forage and make current foraging more secure. We suggest that making provisions for foraging in urban planning goals could contribute to the sustainable development of cities in Africa and elsewhere.
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  • Date Issued: 2023

Unveiling the reactivity of truxillic and truxinic acids (TXAs): deprotonation, anion center dot center dot center dot HO, cation center dot center dot center dot O and cation center dot center dot center dot pi interactions in TXA (0) center dot center dot center dot Y+ and TXA (0) center dot center dot center dot Z (-) complexes (Y= Li, Na, K; Z= F, Cl, Br)

- Isamura, Bienfait K, Patouossa, Issofa, Muya, Jules T, Lobb, Kevin A

  • Authors: Isamura, Bienfait K , Patouossa, Issofa , Muya, Jules T , Lobb, Kevin A
  • Date: 2023
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/452827 , vital:75173 , xlink:href="https://link.springer.com/content/pdf/10.1007/s11224-022-01965-5.pdf"
  • Description: Herein, we report a quantum chemistry investigation of the interaction between µ-truxinic acid, referred to as TXA0 , and Y+ (Y=Li, Na, K) and Z− (Z=F, Cl, Br) ions using M06-2X, B3LYP and 휔 B97XD functionals in conjunction with the 6–31+ +G(d,p), aug-cc-pVDZ(-X2C) and 6–311+ +G (d, p) basis sets. Our computations suggest that Y+ cations can bind to TXA0 through several combinations of cation…O and cation-π interactions, while Z− anions generally establish anion… H–O contacts. Predicted binding energies at the M06-2X/6–311+ +G(d,p) level range between−26.6 and−70.2 kcal/mol for cationic complexes and−20.4 and−62.3 kcal/mol for anionic ones. As such, TXA0 appears as an amphoteric molecule with a slight preference for electrophilic (cation... O) attacks. Furthermore, the most favourable binding site for cations allows for the formation of O…cation…O interactions where the cation is trapped between O37 and O38 atoms of TXA0 . Anions do not behave uniformly towards TXA0 : while the fuoride anion F− induces the deprotonation of TXA0 , Br− and Cl− do not. All of these structural insights are supported by topological calculations in the context of the quantum theory of atoms in molecules (QTAIM). Finally, SAPT0 analyses suggest that TXA0 …Y+ and TXA0 …Z− complexes are mainly stabilized by electrostatic and inductive efects, whose combined contributions account for more than 60 percent of the total interaction energy.
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  • Date Issued: 2023

Using Citizen Science to Protect Natural Untreated Drinking Water Sources: Natural Springs in Rural Catchments and B3 Municipalities in the Eastern Cape

- Mtati, Nosi, Chetty, Preven, Norman, Yondela, Mvulane, Paulose, Libala, Notiswa, Weaver, Matthew J T, Wolff, Margaret M, Cockburn, Jessica J, Mazibuko, Thembalani

  • Authors: Mtati, Nosi , Chetty, Preven , Norman, Yondela , Mvulane, Paulose , Libala, Notiswa , Weaver, Matthew J T , Wolff, Margaret M , Cockburn, Jessica J , Mazibuko, Thembalani
  • Date: 2023
  • Subjects: To be catalogued
  • Language: English
  • Type: text , book
  • Identifier: http://hdl.handle.net/10962/425732 , vital:72279 , ISBN 978-0-6392-0550-2 , https://wrcwebsite.azurewebsites.net/wp-content/uploads/mdocs/3097 final.pdf
  • Description: Citizen science is a well-known mechanism used by researchers to col-lect scientific data working together with citizens. It can also be used by interested and concerned citizens (social activists regarding environ-mental threats) to protect natural occurring things like biodiversity, rare species that are threatened extension and much more. It can be a natu-ral occurring process that evolves with time but it can also have some guidelines of how to monitor, collect, analyse and disseminate data. In this project we used participatory action research processes to co-develop tools (co-create being one of the types of citizen science) with local communities, using their knowledge of their area to monitor and protect natural springs. Springs are useful for providing drinking water for people but also for livestock. In rural areas and small towns where service delivery is not reliable, natural occurring water sources become the reliable supply for these communities. Springs also provide ecosys-tem services as they are a keystone ecological infrastructure. These natural water sources can be threatened by pollution, especially that of livestock which is mostly unattended, because they are sometimes shared by people and animals. This poses health risks to the users. This study co-developed the “spring protection and sustainable use” tool/s that can be used to guide communities and local government on how to protect these important water sources. Citizen science also cre-ates opportunities for learning to take place among the participants as well as the researchers involved.
  • Full Text:
  • Date Issued: 2023

Using Facebook user photos to quantify surface water dependency in Southern African arid-zone bird species

- Dixon, Elizabeth A, Smit, Ben

  • Authors: Dixon, Elizabeth A , Smit, Ben
  • Date: 2023
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/441668 , vital:73905 , https://doi.org/10.1080/01584197.2023.2182223
  • Description: Birds need to maintain their hydration by either gaining water from their food or by drinking surface water. Many arid-zone birds do not need to consume surface water to maintain body condition. Conservationists need to better understand avian use of surface water sources to inform management plans in a warming world. In this study, we explored the use of Facebook’s image search as a tool to predict interspecific variations in avian surface water use. There was a significant correlation between the proportion of Facebook photographs of each species associated with surface water, and surface water use indices for these species based on published field studies. These findings suggest that Facebook may be a useful source of data for determining the dependence of bird species on surface water. Future research could address the potential for Facebook and other social media platforms for answering a range of ecological questions relating to avian water dependency.
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  • Date Issued: 2023

Water, Transport, Oil and Food: A Political–Economy–Ecology Lens on Changing Conceptions of Work, Learning and Skills Development in Africa

- Lotz-Sisitka, Heila

  • Authors: Lotz-Sisitka, Heila
  • Date: 2023
  • Subjects: To be catalogued
  • Language: English
  • Type: text , book chapter
  • Identifier: http://hdl.handle.net/10962/434894 , vital:73114 , ISBN 978-1529224634 , https://bristoluniversitypress.co.uk/transitioning-vocational-education-and-training-in-africa
  • Description: Not enough has been said about the kinds of skills develop-ment that are needed if we are to stem the rising tides and impacts of political economies that have been driving what some call ‘fossil capital’(Malm, 2016). In this book, we are producing an emerging argument that it is necessary to also rethink and reframe vocational education and training (VET) logics and approaches if we are to fully consider the implica-tions of a warming future. This chapter provides the context of why this is such an urgent challenge and some thinking tools for understanding where we have come from and where we need to go. The prognosis is that it is now almost impossible to stop global warming below 2oC. The 2021 In-tergovernmental Panel on Climate Change (IPCC) report is-sued a ‘red alert’for humanity, noting climate change to be one of the most severe challenges facing human societies for decades and potentially centuries to come. Scientists are warning that we have entered a new ‘geological epoch’, named the ‘Anthropocene’, in which human activity, especial-ly the release of carbon dioxide into the atmosphere through fossil-based pollution, is transforming the stability of the earth system and creating knock on effects such as ice melt and methane release, which exacerbate the impacts of pollutants on the stability of the earth system.
  • Full Text:
  • Date Issued: 2023

Wing-moult and seasonal occurrence of sunbirds (Nectariniidae) captured at four sites in the Eastern Cape, South Africa

- Bonnevie, Bo T, Craig, Adrian J F K, Hulley, Patrick E, Schultz, Albert, Tree, Anthony J

  • Authors: Bonnevie, Bo T , Craig, Adrian J F K , Hulley, Patrick E , Schultz, Albert , Tree, Anthony J
  • Date: 2023
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/449607 , vital:74833 , https://doi.org/10.2989/00306525.2022.2075482
  • Description: Ringing activity in the Eastern Cape province, South Africa, spanned 30 years, with three sites active concurrently over a 14-year period, and three sites over a 6-year period. In total, in the course of 714 ringing days, in all months, we handled 1 207 Amethyst Sunbirds, 708 Southern Double-collared Sunbirds, 707 Greater Double-collared Sunbirds, 381 Grey Sunbirds, 121 Malachite Sunbirds and 140 Collared Sunbirds. Although individuals of all six species were recaptured more than five years after ringing, and despite evidence of the seasonal passage of sunbirds at two sites near the Indian Ocean coast, no birds were recaptured away from the original ringing site.
  • Full Text:
  • Date Issued: 2023
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