Servant leadership principle as part of the corporate philosophies of companies
- Authors: Du Plessis, Francine
- Date: 2010
- Subjects: Leadership -- South Africa -- Eastern Cape , Servant leadership -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: vital:9283 , http://hdl.handle.net/10948/1359 , Leadership -- South Africa -- Eastern Cape , Servant leadership -- South Africa -- Eastern Cape
- Description: This research provides insight into the servant leadership principles that are found in the mission, vision and values statements of companies. The primary purpose of this study is to investigate the corporate philosophies of companies to ascertain whether it contains servant leadership principles and thus to what extent these companies may utilise these principles. Mayer, Bardes and Piccolo (2008) state that servant leaders are lead by a moral orientation, which results in the likelihood of them engaging in ethical practices and being unbiased in the decision-making process. The lack of moral and ethical behaviour by leaders indicates that there is a need for a leadership method that is based on ethical practices and moral behaviour. Trompenaars and Voerman (2009) noted that companies who have implemented servant leadership are successful as a result. Spears (2004) indicated that the corporate philosophy of a company should reflect its leadership. This study will therefore aim to identify whether servant leadership principles are evident in the corporate philosophies of companies by using a framework developed to investigate servant leadership. A mixed method empirical research design was applied, using published financial statements to analyse the corporate philosophies of companies. Convenience sampling was used to identify a sample of 100 companies. Fifty companies from the top 200 listed companies at the Johannesburg Stock Exchange in South Africa (JSE) and another fifty companies from the top 100 listed companies at the New York Stock Exchange (NYSE) were included in the sample. The values statements, missions and visions of each company were qualitatively analysed and coded. This resulted in a set of data that could be quantitatively analysed. The results show that the majority of the sample as a whole displayed at least five out of the ten servant leadership principles. The JSE sample only displayed five out of the ten xv servant leadership principles compared to the NYSE sample that displayed seven out of the ten. There was also no statistical significant difference between the results of the respondent companies of the two stock exchanges. The JSE sample referred mostly to the servant leadership principle of Integrity, while the NYSE sample referred mostly to Employee empowerment and development. It can be concluded that servant leadership principles are indeed present in the corporate philosophies of companies listed on both the JSE and the NYSE. However, these principles are present in varying degrees. This study provides research on servant leadership principles by providing an international comparison of the missions, visions and values statements of companies in two countries. The framework developed to investigate servant leadership principles can thus be further extended and used to investigate whether businesses in general are employing these principles.
- Full Text:
- Date Issued: 2010
- Authors: Du Plessis, Francine
- Date: 2010
- Subjects: Leadership -- South Africa -- Eastern Cape , Servant leadership -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: vital:9283 , http://hdl.handle.net/10948/1359 , Leadership -- South Africa -- Eastern Cape , Servant leadership -- South Africa -- Eastern Cape
- Description: This research provides insight into the servant leadership principles that are found in the mission, vision and values statements of companies. The primary purpose of this study is to investigate the corporate philosophies of companies to ascertain whether it contains servant leadership principles and thus to what extent these companies may utilise these principles. Mayer, Bardes and Piccolo (2008) state that servant leaders are lead by a moral orientation, which results in the likelihood of them engaging in ethical practices and being unbiased in the decision-making process. The lack of moral and ethical behaviour by leaders indicates that there is a need for a leadership method that is based on ethical practices and moral behaviour. Trompenaars and Voerman (2009) noted that companies who have implemented servant leadership are successful as a result. Spears (2004) indicated that the corporate philosophy of a company should reflect its leadership. This study will therefore aim to identify whether servant leadership principles are evident in the corporate philosophies of companies by using a framework developed to investigate servant leadership. A mixed method empirical research design was applied, using published financial statements to analyse the corporate philosophies of companies. Convenience sampling was used to identify a sample of 100 companies. Fifty companies from the top 200 listed companies at the Johannesburg Stock Exchange in South Africa (JSE) and another fifty companies from the top 100 listed companies at the New York Stock Exchange (NYSE) were included in the sample. The values statements, missions and visions of each company were qualitatively analysed and coded. This resulted in a set of data that could be quantitatively analysed. The results show that the majority of the sample as a whole displayed at least five out of the ten servant leadership principles. The JSE sample only displayed five out of the ten xv servant leadership principles compared to the NYSE sample that displayed seven out of the ten. There was also no statistical significant difference between the results of the respondent companies of the two stock exchanges. The JSE sample referred mostly to the servant leadership principle of Integrity, while the NYSE sample referred mostly to Employee empowerment and development. It can be concluded that servant leadership principles are indeed present in the corporate philosophies of companies listed on both the JSE and the NYSE. However, these principles are present in varying degrees. This study provides research on servant leadership principles by providing an international comparison of the missions, visions and values statements of companies in two countries. The framework developed to investigate servant leadership principles can thus be further extended and used to investigate whether businesses in general are employing these principles.
- Full Text:
- Date Issued: 2010
Service delivery challenges : King Sabata Dalindyebo local municipality : Mthatha
- Authors: Gwayi, Melwin Sandile
- Date: 2010
- Subjects: Municipal services -- South Africa -- Eastern Cape , Local government -- South Africa -- Eastern Cape , Economic development projects -- South Africa -- Eastern Cape , Municipal government -- South Africa -- Eastern Cape , King Sabata Dalindyebo Municipality
- Language: English
- Type: Thesis , Masters , MPA
- Identifier: vital:8177 , http://hdl.handle.net/10948/1541 , Municipal services -- South Africa -- Eastern Cape , Local government -- South Africa -- Eastern Cape , Economic development projects -- South Africa -- Eastern Cape , Municipal government -- South Africa -- Eastern Cape , King Sabata Dalindyebo Municipality
- Description: This study aims to achieve the following four research objectives: - To investigate the challenges that led to the KSDLM experiencing poor municipal service delivery, and its constraints to effective implementation of the IDP. - To develop and propose effective strategies for the continuous improvement of service delivery and good governance in KSDLM with specific reference to the town of Mthatha. - To reveal counterproductive variances between legislation and governance instruments crafted by the municipality which may, as a result of misinterpretation, result in distortions in carrying out the Constitutional mandate. - To work towards achieving conclusive findings to assist political office-bearers at national and provincial sphere to formulate legislation to promote the local government’s effectiveness and efficiency.
- Full Text:
- Date Issued: 2010
- Authors: Gwayi, Melwin Sandile
- Date: 2010
- Subjects: Municipal services -- South Africa -- Eastern Cape , Local government -- South Africa -- Eastern Cape , Economic development projects -- South Africa -- Eastern Cape , Municipal government -- South Africa -- Eastern Cape , King Sabata Dalindyebo Municipality
- Language: English
- Type: Thesis , Masters , MPA
- Identifier: vital:8177 , http://hdl.handle.net/10948/1541 , Municipal services -- South Africa -- Eastern Cape , Local government -- South Africa -- Eastern Cape , Economic development projects -- South Africa -- Eastern Cape , Municipal government -- South Africa -- Eastern Cape , King Sabata Dalindyebo Municipality
- Description: This study aims to achieve the following four research objectives: - To investigate the challenges that led to the KSDLM experiencing poor municipal service delivery, and its constraints to effective implementation of the IDP. - To develop and propose effective strategies for the continuous improvement of service delivery and good governance in KSDLM with specific reference to the town of Mthatha. - To reveal counterproductive variances between legislation and governance instruments crafted by the municipality which may, as a result of misinterpretation, result in distortions in carrying out the Constitutional mandate. - To work towards achieving conclusive findings to assist political office-bearers at national and provincial sphere to formulate legislation to promote the local government’s effectiveness and efficiency.
- Full Text:
- Date Issued: 2010
Service quality perceptions in the Uganda mobile telephone branch of industry
- Authors: Byarugaba, Jotham Mbiito
- Date: 2010
- Subjects: Cell phone services industry -- Uganda , Service industries -- Uganda -- Quality control , Cell phones -- Uganda -- Design , Consumer satisfaction -- Uganda
- Language: English
- Type: Thesis , Doctoral , DCom
- Identifier: vital:9373 , http://hdl.handle.net/10948/1226
- Description: Standard practice dictates that mobile telephone service providers remain accurately aligned with the dynamic expectations structure of the target mobile telephone service users they serve. To comply with this requirement, literature sources assert that service providers need to adopt a candid marketing research orientation to understand what the users expect and in-build it in their service designs. Theory further contends that if such a business stance is diligently applied, any service provider is bound to gain a competitive edge in the market place. Notwithstanding the aforementioned, service providers continue design services without sufficient understanding of what users expect. This mindset has led to disparities in both the designed and the recieved service. Despite the pioneering works of earlier reserachers on the Gaps model, evidence shows that no research had been carried out to measure users' and providers' service quality perceptions in the mobile telephone branch of industry in Uganda. Much remains unknown as regards users' perceptions of expected and actual service quality and any potential disparity thereof. In the same spirit, much remains unknown as regards providers' perceptions of users' expectations and users' real expectations and potential disparity thereof. In order to measure the aforementioned disparities, the Gaps model was used in which Gaps 1 and 5 were measured for providers and users of mobile telephone services in the branch industry in Uganda.
- Full Text: false
- Date Issued: 2010
- Authors: Byarugaba, Jotham Mbiito
- Date: 2010
- Subjects: Cell phone services industry -- Uganda , Service industries -- Uganda -- Quality control , Cell phones -- Uganda -- Design , Consumer satisfaction -- Uganda
- Language: English
- Type: Thesis , Doctoral , DCom
- Identifier: vital:9373 , http://hdl.handle.net/10948/1226
- Description: Standard practice dictates that mobile telephone service providers remain accurately aligned with the dynamic expectations structure of the target mobile telephone service users they serve. To comply with this requirement, literature sources assert that service providers need to adopt a candid marketing research orientation to understand what the users expect and in-build it in their service designs. Theory further contends that if such a business stance is diligently applied, any service provider is bound to gain a competitive edge in the market place. Notwithstanding the aforementioned, service providers continue design services without sufficient understanding of what users expect. This mindset has led to disparities in both the designed and the recieved service. Despite the pioneering works of earlier reserachers on the Gaps model, evidence shows that no research had been carried out to measure users' and providers' service quality perceptions in the mobile telephone branch of industry in Uganda. Much remains unknown as regards users' perceptions of expected and actual service quality and any potential disparity thereof. In the same spirit, much remains unknown as regards providers' perceptions of users' expectations and users' real expectations and potential disparity thereof. In order to measure the aforementioned disparities, the Gaps model was used in which Gaps 1 and 5 were measured for providers and users of mobile telephone services in the branch industry in Uganda.
- Full Text: false
- Date Issued: 2010
Sexy sports: a reception study of the National Broadcasting Corporation (NBC) Olympics website coverage of women's beach volleyball at the 2008 Beijing Olympics
- Authors: Tajdin, Wafa Mohamed
- Date: 2010
- Subjects: Olympics National Broadcasting Company Sports journalism Mass media and sports Volleyball for women Beach volleyball Feminism and mass media Cyberfeminism Sexism in mass media Women athletes Sports for women Sex role in mass media Women in mass media
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3486 , http://hdl.handle.net/10962/d1002941
- Description: Sexy Sports: A reception study of the National Broadcasting Corporation (NBC) Olympics website coverage of women’s beach volleyball at the 2008 Beijing Olympics involves an examination of the sporting media and its reportage of the female athlete. The thesis will focus on the reception of the NBC Olympics website coverage of women’s beach volleyball at the 2008 Beijing Olympics by viewing groups constituted by the researcher. The reason for this is that it would be difficult to find naturally constituted audiences for this website, but its reception is never-the-less of research interest. My hypothesis is that the nature of the images and text on the website is overdetermined by the construction of women on other popular texts such as men’s magazines etc. In focusing on the meanings obtained from the content of the website (texts and images), the study will investigate how these meanings are naturalised in specific moments of production as well as through their intertextual relationships with similar texts involved in the glamorisation of female athletes. Specifically the study explores the meanings obtained from the content of the website (texts and images) and how in turn these meanings are naturalised by the consumers of the website. The study will utilise a qualitative research design to unpack the content of the website through the use of qualitative content analysis, focus group interviews and individual in-depth interviews. The research will be informed via a theoretical framework that draws from feminist theory, sport feminism, the concept of intertextuality between media texts, ideology and Stuart Hall’s model of preferred reading. Increasingly mainstream media uses the image of a woman’s body to sell almost anything from men’s razors to margarine and in so far as the reporting of women’s sports is concerned this holds true. Through the research I intend to account for the connotative power of other texts i.e. the men’s magazines and pornography, and how this is likely to be carried through into shaping the meanings that are read off the website. Arguably the production of the NBC texts and images are overdetermined by the existence of similar texts already in transmission in the circuit of culture.
- Full Text:
- Date Issued: 2010
- Authors: Tajdin, Wafa Mohamed
- Date: 2010
- Subjects: Olympics National Broadcasting Company Sports journalism Mass media and sports Volleyball for women Beach volleyball Feminism and mass media Cyberfeminism Sexism in mass media Women athletes Sports for women Sex role in mass media Women in mass media
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3486 , http://hdl.handle.net/10962/d1002941
- Description: Sexy Sports: A reception study of the National Broadcasting Corporation (NBC) Olympics website coverage of women’s beach volleyball at the 2008 Beijing Olympics involves an examination of the sporting media and its reportage of the female athlete. The thesis will focus on the reception of the NBC Olympics website coverage of women’s beach volleyball at the 2008 Beijing Olympics by viewing groups constituted by the researcher. The reason for this is that it would be difficult to find naturally constituted audiences for this website, but its reception is never-the-less of research interest. My hypothesis is that the nature of the images and text on the website is overdetermined by the construction of women on other popular texts such as men’s magazines etc. In focusing on the meanings obtained from the content of the website (texts and images), the study will investigate how these meanings are naturalised in specific moments of production as well as through their intertextual relationships with similar texts involved in the glamorisation of female athletes. Specifically the study explores the meanings obtained from the content of the website (texts and images) and how in turn these meanings are naturalised by the consumers of the website. The study will utilise a qualitative research design to unpack the content of the website through the use of qualitative content analysis, focus group interviews and individual in-depth interviews. The research will be informed via a theoretical framework that draws from feminist theory, sport feminism, the concept of intertextuality between media texts, ideology and Stuart Hall’s model of preferred reading. Increasingly mainstream media uses the image of a woman’s body to sell almost anything from men’s razors to margarine and in so far as the reporting of women’s sports is concerned this holds true. Through the research I intend to account for the connotative power of other texts i.e. the men’s magazines and pornography, and how this is likely to be carried through into shaping the meanings that are read off the website. Arguably the production of the NBC texts and images are overdetermined by the existence of similar texts already in transmission in the circuit of culture.
- Full Text:
- Date Issued: 2010
Shark fishing effort and catch of the ragged-tooth shark Carcharias taurus in the South African competitive shore-angling fishery
- Dicken, Matthew L, Booth, Anthony J, Smale, Malcolm J
- Authors: Dicken, Matthew L , Booth, Anthony J , Smale, Malcolm J
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/126944 , vital:35937 , https://doi.10.2989/18142320609504209
- Description: In South Africa, Carcharias taurus is commonly known as the ragged-tooth shark or raggie. The species is also referred to as the sand-tiger shark in North America and as the grey-nurse shark in Australia. It is a long-lived species with an estimated longevity of up to 40 years (Goldman 2002). Female sharks reach sexual maturity at approximately 10 years (Goldman 2002), and they exhibit a biennial reproductive cycle (Branstetter and Musick 1994, Lucifora et al. 2002, G Cliff, Natal Sharks Board, unpublished data). Intra-uterine cannibalisation results in a maximum fecundity of two pups per litter after a gestation period of approximately 9–12 months (Bass et al. 1975, Gilmore et al. 1983). These life-history characteristics make this species particularly susceptible to overexploitation.
- Full Text:
- Date Issued: 2010
- Authors: Dicken, Matthew L , Booth, Anthony J , Smale, Malcolm J
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/126944 , vital:35937 , https://doi.10.2989/18142320609504209
- Description: In South Africa, Carcharias taurus is commonly known as the ragged-tooth shark or raggie. The species is also referred to as the sand-tiger shark in North America and as the grey-nurse shark in Australia. It is a long-lived species with an estimated longevity of up to 40 years (Goldman 2002). Female sharks reach sexual maturity at approximately 10 years (Goldman 2002), and they exhibit a biennial reproductive cycle (Branstetter and Musick 1994, Lucifora et al. 2002, G Cliff, Natal Sharks Board, unpublished data). Intra-uterine cannibalisation results in a maximum fecundity of two pups per litter after a gestation period of approximately 9–12 months (Bass et al. 1975, Gilmore et al. 1983). These life-history characteristics make this species particularly susceptible to overexploitation.
- Full Text:
- Date Issued: 2010
Sheep production practices, flock dynamics, body condition and weight variation in two ecologically different resource-poor communal farming systems
- Authors: Mapiliyao, Luke
- Date: 2010
- Subjects: Sheep -- Breeding -- South Africa -- Eastern Cape , Sheep breeds -- South Africa -- Eastern Cape , Communal rangelands -- South Africa -- Eastern Cape , Sheep ranchers -- South Africa -- Eastern Cape , Sheep -- Feeding and feeds -- South Africa -- Eastern Cape , Forage , Grazing -- South Africa -- Eastern Cape , Sheep -- Diseases -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc Agric (Animal Science)
- Identifier: vital:11816 , http://hdl.handle.net/10353/340 , http://hdl.handle.net/10353/d1001041 , Sheep -- Breeding -- South Africa -- Eastern Cape , Sheep breeds -- South Africa -- Eastern Cape , Communal rangelands -- South Africa -- Eastern Cape , Sheep ranchers -- South Africa -- Eastern Cape , Sheep -- Feeding and feeds -- South Africa -- Eastern Cape , Forage , Grazing -- South Africa -- Eastern Cape , Sheep -- Diseases -- South Africa -- Eastern Cape
- Description: The objective of this study was to determine sheep production practices, constraints, flock dynamics, body condition and weight variation in two ecologically different resource-poor communal farming systems of the Eastern Cape Province of South Africa. Mean sheep flock sizes per household were not significantly different between the two ecologically different areas (villages); Gaga (19.0±3.10) and Sompondo (18.3±3.10). Shortage of feed, disease and parasite were reported the most important constraints across the two villages. In both villages, sheep housing was poorly constructed using acacia brushwoods. Fewer farmers owned rams: the rams to ewes ratio for the two villages were 1:20, 1:19 for Gaga and Sompondo, respectively. The low ram: ewe ratios reported suggest that inbreeding might have been reducing productivity of their flocks. There was also uncontrolled breeding due to undefined and mating seasons. Gall sickness, heart water and footrot caused most of the sheep mortalities. Dohne Merinos were the common genotypes in the two villages. Total entrances for each flock were higher (p < 0.05) in hot-dry season and hot-wet season than in other seasons. Most of the entrances were lambs and were born in hot-dry season (September) and cool-dry season (June) for larger flocks (10.90 ± 3.02) and for small flocks (3.65 ± 3.02). High lamb mortalities were experienced in the post-rainy (April) and hot-wet (December) season. There was a significant interaction between season and flock size. Most of the sales occurred in the hot-wet season. Ecological area had significant effect on sheep production potential (p < 0.05) in both flock classes. The average sheep production efficiency (SPE) value for Gaga and Sompondo were 0.50 ± 0.116 and 0.50 ± 0.096 respectively. The SPE for large flock was higher (p < 0.05) by season and flock size. Large flocks had a higher (p < 0.05) SPE values and the SPE ranged from 1.11 ± 0.193 in April, a post-rainy season month to 1.55 ± 0.193 in December, a hot-wet season month. Lamb mortalities constituted the greater part of outflows. High lamb mortalities occurred in hot-wet (December), hot-dry (September) and post-rainy (April) seasons. There was a significant interaction between season and age of sheep on body weight of sheep. Highest (p < 0.05) body weights were recorded in the post-rainy and autumn season in both lambs and ewes. It is therefore very important to come up with affordable interventions which take into play ecological differences of the areas for improved nutritional status of sheep in communal areas which will lead to improved sheep productivity and the poor-resourced farmer human nutritional and livelihood.
- Full Text:
- Date Issued: 2010
- Authors: Mapiliyao, Luke
- Date: 2010
- Subjects: Sheep -- Breeding -- South Africa -- Eastern Cape , Sheep breeds -- South Africa -- Eastern Cape , Communal rangelands -- South Africa -- Eastern Cape , Sheep ranchers -- South Africa -- Eastern Cape , Sheep -- Feeding and feeds -- South Africa -- Eastern Cape , Forage , Grazing -- South Africa -- Eastern Cape , Sheep -- Diseases -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc Agric (Animal Science)
- Identifier: vital:11816 , http://hdl.handle.net/10353/340 , http://hdl.handle.net/10353/d1001041 , Sheep -- Breeding -- South Africa -- Eastern Cape , Sheep breeds -- South Africa -- Eastern Cape , Communal rangelands -- South Africa -- Eastern Cape , Sheep ranchers -- South Africa -- Eastern Cape , Sheep -- Feeding and feeds -- South Africa -- Eastern Cape , Forage , Grazing -- South Africa -- Eastern Cape , Sheep -- Diseases -- South Africa -- Eastern Cape
- Description: The objective of this study was to determine sheep production practices, constraints, flock dynamics, body condition and weight variation in two ecologically different resource-poor communal farming systems of the Eastern Cape Province of South Africa. Mean sheep flock sizes per household were not significantly different between the two ecologically different areas (villages); Gaga (19.0±3.10) and Sompondo (18.3±3.10). Shortage of feed, disease and parasite were reported the most important constraints across the two villages. In both villages, sheep housing was poorly constructed using acacia brushwoods. Fewer farmers owned rams: the rams to ewes ratio for the two villages were 1:20, 1:19 for Gaga and Sompondo, respectively. The low ram: ewe ratios reported suggest that inbreeding might have been reducing productivity of their flocks. There was also uncontrolled breeding due to undefined and mating seasons. Gall sickness, heart water and footrot caused most of the sheep mortalities. Dohne Merinos were the common genotypes in the two villages. Total entrances for each flock were higher (p < 0.05) in hot-dry season and hot-wet season than in other seasons. Most of the entrances were lambs and were born in hot-dry season (September) and cool-dry season (June) for larger flocks (10.90 ± 3.02) and for small flocks (3.65 ± 3.02). High lamb mortalities were experienced in the post-rainy (April) and hot-wet (December) season. There was a significant interaction between season and flock size. Most of the sales occurred in the hot-wet season. Ecological area had significant effect on sheep production potential (p < 0.05) in both flock classes. The average sheep production efficiency (SPE) value for Gaga and Sompondo were 0.50 ± 0.116 and 0.50 ± 0.096 respectively. The SPE for large flock was higher (p < 0.05) by season and flock size. Large flocks had a higher (p < 0.05) SPE values and the SPE ranged from 1.11 ± 0.193 in April, a post-rainy season month to 1.55 ± 0.193 in December, a hot-wet season month. Lamb mortalities constituted the greater part of outflows. High lamb mortalities occurred in hot-wet (December), hot-dry (September) and post-rainy (April) seasons. There was a significant interaction between season and age of sheep on body weight of sheep. Highest (p < 0.05) body weights were recorded in the post-rainy and autumn season in both lambs and ewes. It is therefore very important to come up with affordable interventions which take into play ecological differences of the areas for improved nutritional status of sheep in communal areas which will lead to improved sheep productivity and the poor-resourced farmer human nutritional and livelihood.
- Full Text:
- Date Issued: 2010
Shifting between Bodies and Words: Writing and performing the butoh dance, Amanogawa
- Authors: Gordon, Gary E
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/468617 , vital:77097 , https://doi.org/10.1080/10137548.2010.9687919
- Description:
- Full Text:
- Date Issued: 2010
- Authors: Gordon, Gary E
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/468617 , vital:77097 , https://doi.org/10.1080/10137548.2010.9687919
- Description:
- Full Text:
- Date Issued: 2010
Simultaneous determination of irinotecan hydrochloride and its related compounds by high performance liquid chromatography using ultraviolet detection
- Mohammadi, Ali, Esmaeili, Farnaz, Dinarvand, Rassoul, Atyabi, Fatemeh, Walker, Roderick B
- Authors: Mohammadi, Ali , Esmaeili, Farnaz , Dinarvand, Rassoul , Atyabi, Fatemeh , Walker, Roderick B
- Date: 2010
- Language: English
- Type: Article
- Identifier: vital:6413 , http://hdl.handle.net/10962/d1006508
- Description: A new simple, precise and accurate high performance liquid chromatography (HPLC) method was developed and validated for the simultaneous determination of irinotecan (CPT-11) and two related compounds viz., 7-ethyl-10 hydroxycamptothecin (SN-38) and camptothecin (CPT) in pharmaceutical dosage forms. Chromatography was accomplished using a reversed-phase C18 column and ultraviolet (UV)detection and an isocratic mobile phase consisting of 3 % v/v triethylammonium acetate buffer (pH 3) and acetonitrile (70:30 v/v). The linear range of quantitation for all the compounds was 0.1-10 μg/mL. The limit of quantitation for all the compounds ranged between 0.01-0.05 μg/mL. The method has the requisite accuracy, selectivity, sensitivity and precision to assay of CPT-11 and related compounds in pharmaceutical dosage forms and bulk API.
- Full Text:
- Date Issued: 2010
- Authors: Mohammadi, Ali , Esmaeili, Farnaz , Dinarvand, Rassoul , Atyabi, Fatemeh , Walker, Roderick B
- Date: 2010
- Language: English
- Type: Article
- Identifier: vital:6413 , http://hdl.handle.net/10962/d1006508
- Description: A new simple, precise and accurate high performance liquid chromatography (HPLC) method was developed and validated for the simultaneous determination of irinotecan (CPT-11) and two related compounds viz., 7-ethyl-10 hydroxycamptothecin (SN-38) and camptothecin (CPT) in pharmaceutical dosage forms. Chromatography was accomplished using a reversed-phase C18 column and ultraviolet (UV)detection and an isocratic mobile phase consisting of 3 % v/v triethylammonium acetate buffer (pH 3) and acetonitrile (70:30 v/v). The linear range of quantitation for all the compounds was 0.1-10 μg/mL. The limit of quantitation for all the compounds ranged between 0.01-0.05 μg/mL. The method has the requisite accuracy, selectivity, sensitivity and precision to assay of CPT-11 and related compounds in pharmaceutical dosage forms and bulk API.
- Full Text:
- Date Issued: 2010
Site of struggle: the Freedom Park fracas and the divisive legacy of South Africa’s Border War/Liberation Struggle
- Authors: Baines, Gary F
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/126954 , vital:35938 , https://doi.10.1080/02533950903076428
- Description: In South Africa, Carcharias taurus is commonly known as the ragged-tooth shark or raggie. The species is also referred to as the sand-tiger shark in North America and as the grey-nurse shark in Australia. It is a long-lived species with an estimated longevity of up to 40 years (Goldman 2002). Female sharks reach sexual maturity at approximately 10 years (Goldman 2002), and they exhibit a biennial reproductive cycle (Branstetter and Musick 1994, Lucifora et al. 2002, G Cliff, Natal Sharks Board, unpublished data). Intra-uterine cannibalisation results in a maximum fecundity of two pups per litter after a gestation period of approximately 9–12 months (Bass et al. 1975, Gilmore et al. 1983). These life-history characteristics make this species particularly susceptible to overexploitation.
- Full Text:
- Date Issued: 2010
- Authors: Baines, Gary F
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/126954 , vital:35938 , https://doi.10.1080/02533950903076428
- Description: In South Africa, Carcharias taurus is commonly known as the ragged-tooth shark or raggie. The species is also referred to as the sand-tiger shark in North America and as the grey-nurse shark in Australia. It is a long-lived species with an estimated longevity of up to 40 years (Goldman 2002). Female sharks reach sexual maturity at approximately 10 years (Goldman 2002), and they exhibit a biennial reproductive cycle (Branstetter and Musick 1994, Lucifora et al. 2002, G Cliff, Natal Sharks Board, unpublished data). Intra-uterine cannibalisation results in a maximum fecundity of two pups per litter after a gestation period of approximately 9–12 months (Bass et al. 1975, Gilmore et al. 1983). These life-history characteristics make this species particularly susceptible to overexploitation.
- Full Text:
- Date Issued: 2010
Small hospitality enterprises and the internet: an IT governance model for conducting business online
- Authors: Ngoqo, Bukelwa
- Date: 2010
- Subjects: Hospitality industry -- South Africa , Tourism -- South Africa , Organizational effectiveness -- South Africa , Electronic commerce , Internet , Risk management , Electronic data processing
- Language: English
- Type: Thesis , Masters , MCom (Information Systems)
- Identifier: vital:11133 , http://hdl.handle.net/10353/382 , Hospitality industry -- South Africa , Tourism -- South Africa , Organizational effectiveness -- South Africa , Electronic commerce , Internet , Risk management , Electronic data processing
- Description: The Internet has made a considerable impact on how business is conducted. Empowered by technology consumers are using the Internet as a tool to communicate and transact online. E-commerce (electronic commerce) presents opportunities for business to gain a competitive advantage, however it also posses certain challenges. Small and Medium Hospitality Enterprises (SMHEs) sector within the tourism industry, is one of the sectors which stands to benefit from using the Internet for business. Researchers agree that the contribution made by the tourism sector in developing economies is substantial. However, SMHEs are noted for their failure to derive optimal benefits from using the Internet for business to improve their competitiveness. This study which seeks to develop a model for use by SMHEs as a guide when making the decision to adopt technology was necessitated by the importance of SMHE’s contribution in the economy of developing countries. This model is based on the examination of existing theories and models such as; the Delone and McLean IS success model (2004), and the ITGI’s (2007) IT governance focus areas model. To elicit the desired outcomes, additional data was collected using questionnaires, interviews, and observations. The collected data was analysed and resulted in the development of a model that can be used by SMHEs in order to derive value from IT and to gain a competitive advantage.
- Full Text:
- Date Issued: 2010
- Authors: Ngoqo, Bukelwa
- Date: 2010
- Subjects: Hospitality industry -- South Africa , Tourism -- South Africa , Organizational effectiveness -- South Africa , Electronic commerce , Internet , Risk management , Electronic data processing
- Language: English
- Type: Thesis , Masters , MCom (Information Systems)
- Identifier: vital:11133 , http://hdl.handle.net/10353/382 , Hospitality industry -- South Africa , Tourism -- South Africa , Organizational effectiveness -- South Africa , Electronic commerce , Internet , Risk management , Electronic data processing
- Description: The Internet has made a considerable impact on how business is conducted. Empowered by technology consumers are using the Internet as a tool to communicate and transact online. E-commerce (electronic commerce) presents opportunities for business to gain a competitive advantage, however it also posses certain challenges. Small and Medium Hospitality Enterprises (SMHEs) sector within the tourism industry, is one of the sectors which stands to benefit from using the Internet for business. Researchers agree that the contribution made by the tourism sector in developing economies is substantial. However, SMHEs are noted for their failure to derive optimal benefits from using the Internet for business to improve their competitiveness. This study which seeks to develop a model for use by SMHEs as a guide when making the decision to adopt technology was necessitated by the importance of SMHE’s contribution in the economy of developing countries. This model is based on the examination of existing theories and models such as; the Delone and McLean IS success model (2004), and the ITGI’s (2007) IT governance focus areas model. To elicit the desired outcomes, additional data was collected using questionnaires, interviews, and observations. The collected data was analysed and resulted in the development of a model that can be used by SMHEs in order to derive value from IT and to gain a competitive advantage.
- Full Text:
- Date Issued: 2010
Small town regeneration as a strategy for rural development : case study of Keiskammahoek
- Authors: Qayi, Sandiswa
- Date: 2010
- Subjects: Rural development -- South Africa Case studies , Strategic planning -- South Africa -- Eastern Cape , Economic development projects -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:8654 , http://hdl.handle.net/10948/1361 , Rural development -- South Africa Case studies , Strategic planning -- South Africa -- Eastern Cape , Economic development projects -- South Africa -- Eastern Cape
- Description: The aim of this chapter is to provide an overview of the research topic, conceptualising and defining three critical concepts that the research will focus on. The first part deals with the South African understanding of local economic development, rural development, as well as the role of small towns to local economic development. In order to present the role of small towns in rural economic development it is important to define and contextualise the current meaning and understanding of rural development and local economic development. How small towns can promote the role of rural economic development particularly in relation to their surrounding rural villages. The chapter also briefly introduces the small town of Keiskammahoek as research study area.
- Full Text:
- Date Issued: 2010
- Authors: Qayi, Sandiswa
- Date: 2010
- Subjects: Rural development -- South Africa Case studies , Strategic planning -- South Africa -- Eastern Cape , Economic development projects -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:8654 , http://hdl.handle.net/10948/1361 , Rural development -- South Africa Case studies , Strategic planning -- South Africa -- Eastern Cape , Economic development projects -- South Africa -- Eastern Cape
- Description: The aim of this chapter is to provide an overview of the research topic, conceptualising and defining three critical concepts that the research will focus on. The first part deals with the South African understanding of local economic development, rural development, as well as the role of small towns to local economic development. In order to present the role of small towns in rural economic development it is important to define and contextualise the current meaning and understanding of rural development and local economic development. How small towns can promote the role of rural economic development particularly in relation to their surrounding rural villages. The chapter also briefly introduces the small town of Keiskammahoek as research study area.
- Full Text:
- Date Issued: 2010
Social learning processes and nature-culture relations of commercial beekeeping practices as small and medium enterprise development in Zimbabwe
- Authors: Masara, Christopher
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/386545 , vital:68150 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/122860"
- Description: This paper explores social learning processes and nature-culture relations in a context of transition from traditional to commercial beekeeping in Zimbabwe. The contours of social learning provided by Wals (2007) are used to probe the learning processes in the social interactions shaping an emerging community of commercial beekeepers and their small and medium enterprise development practices. The paper illustrates how the practice of engaging communities in participatory expansive learning research could benefit from more refined tools for understanding the open-ended contours of social learning interactions in relation to nature-culture relations.
- Full Text:
- Date Issued: 2010
- Authors: Masara, Christopher
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/386545 , vital:68150 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/122860"
- Description: This paper explores social learning processes and nature-culture relations in a context of transition from traditional to commercial beekeeping in Zimbabwe. The contours of social learning provided by Wals (2007) are used to probe the learning processes in the social interactions shaping an emerging community of commercial beekeepers and their small and medium enterprise development practices. The paper illustrates how the practice of engaging communities in participatory expansive learning research could benefit from more refined tools for understanding the open-ended contours of social learning interactions in relation to nature-culture relations.
- Full Text:
- Date Issued: 2010
Social relationships and identity online and offline: a study of the interplay between offline social relationships and facebook usage by Rhodes University students from socially disadvantaged backgrounds
- Authors: Chatora, Arther Tichaona
- Date: 2010
- Subjects: Facebook (Electronic resource) Online social networks Information technology -- Social aspects Identity (Psychology) and mass media Rhodes University -- Students -- Social life and customs Rhodes University -- Students -- Social networks Rhodes University -- Students -- Social conditions
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3421 , http://hdl.handle.net/10962/d1002874
- Description: Based on in-depth focus group and individual interviews, this thesis examines how Rhodes University students from socially disadvantaged backgrounds experience campus social life and how they subsequently use Facebook to perform, represent and negotiate their social identities. The study discusses utopian and dystopian positions and interrogates these theoretical perspectives in relation to the students‟ Facebook usage. The popularity and uptake of Facebook by students from disadvantaged backgrounds, such as those here at Rhodes University, is a growing phenomenon, provoking questions about the relationship between social experiences, social identity and social networks. Rhodes University‟s social space has been identified by previous studies as modern, liberal, “elite” and divided along race and class lines. The ways in which students experience this campus social space relates to their subject positions and identities. The study employs different perspectives of identity construction to interrogate the students‟ subject experiences in home and school contexts before coming to Rhodes University. The students‟ subjective positions are primarily embedded in tradition and their subject positions are sometimes in tension or come in conflict with the modern and liberal elements permitted by the Rhodes University context. The students also experience and adopt modern and liberal elements in their lifestyles which are permitted within the Rhodes University social space. The thesis found that Facebook offers a platform which facilitates a social connectivity that influences how students perform their identities in relation to their offline social identities and lived social experiences. This study concludes that the mediated symbolic materials for the construction and negotiation of identity provided by Facebook are sometimes in tension with the demands of traditional subjectivities experienced by these students at Rhodes University. Facebook allows the students to reinforce and affirm the validity of their traditional identities in this modern and liberal space. However, it also emerged that Facebook facilitates and allows students who experience and incorporate the modern and liberal elements permitted at Rhodes University to represent and negotiate their subjective positions online. The findings of the study indicate that participants primarily communicate with their friends, families, relatives and acquaintances - people they know personally offline, in line with the theoretical position which argues that online relationships are primarily shaped by offline relationships.
- Full Text:
- Date Issued: 2010
- Authors: Chatora, Arther Tichaona
- Date: 2010
- Subjects: Facebook (Electronic resource) Online social networks Information technology -- Social aspects Identity (Psychology) and mass media Rhodes University -- Students -- Social life and customs Rhodes University -- Students -- Social networks Rhodes University -- Students -- Social conditions
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3421 , http://hdl.handle.net/10962/d1002874
- Description: Based on in-depth focus group and individual interviews, this thesis examines how Rhodes University students from socially disadvantaged backgrounds experience campus social life and how they subsequently use Facebook to perform, represent and negotiate their social identities. The study discusses utopian and dystopian positions and interrogates these theoretical perspectives in relation to the students‟ Facebook usage. The popularity and uptake of Facebook by students from disadvantaged backgrounds, such as those here at Rhodes University, is a growing phenomenon, provoking questions about the relationship between social experiences, social identity and social networks. Rhodes University‟s social space has been identified by previous studies as modern, liberal, “elite” and divided along race and class lines. The ways in which students experience this campus social space relates to their subject positions and identities. The study employs different perspectives of identity construction to interrogate the students‟ subject experiences in home and school contexts before coming to Rhodes University. The students‟ subjective positions are primarily embedded in tradition and their subject positions are sometimes in tension or come in conflict with the modern and liberal elements permitted by the Rhodes University context. The students also experience and adopt modern and liberal elements in their lifestyles which are permitted within the Rhodes University social space. The thesis found that Facebook offers a platform which facilitates a social connectivity that influences how students perform their identities in relation to their offline social identities and lived social experiences. This study concludes that the mediated symbolic materials for the construction and negotiation of identity provided by Facebook are sometimes in tension with the demands of traditional subjectivities experienced by these students at Rhodes University. Facebook allows the students to reinforce and affirm the validity of their traditional identities in this modern and liberal space. However, it also emerged that Facebook facilitates and allows students who experience and incorporate the modern and liberal elements permitted at Rhodes University to represent and negotiate their subjective positions online. The findings of the study indicate that participants primarily communicate with their friends, families, relatives and acquaintances - people they know personally offline, in line with the theoretical position which argues that online relationships are primarily shaped by offline relationships.
- Full Text:
- Date Issued: 2010
Social sustainability of biogas production in Sogwala village, lower Gweru district, Zimbabwe
- Authors: Dhliwayo, Nyaradzo
- Date: 2010
- Subjects: Biogas -- Zimbabwe , Biogas -- Developing countries , Sustainability -- Zimbabwe
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:10648 , http://hdl.handle.net/10948/1459 , Biogas -- Zimbabwe , Biogas -- Developing countries , Sustainability -- Zimbabwe
- Description: The study has explored the social sustainability of biogas production in a local village of Sogwala which is located in the Lower Gweru District of Zimbabwe. The social sustainability assessment was based on the two concepts of social sustainability, namely human capital and social capital with particular emphasis on their respective elements and aspects. Qualitative and quantitative research methodology methods were used on a sample of 100 households using biogas and some key informants. Analysis of the variance was used to determine whether biogas production could account for any effects on the social and human capital elements of the Sogwala community. An overview and descriptive statistics analysis of the findings from the study have been provided where the biogas users’ experiences, perspectives are discussed and results were assessed. For instance, effects on the aspects of social capital elements which include increases in the social group membership of households after the introduction of biogas production the village; the performance of biogas energy as compared with other fuel sources in terms of accessibility, efficiency and the degree of labour needed for continual production of biogas. In view of the human capital element, assessment is done on the economic status per household before and after the production of biogas, where emphasis is placed on the aspects of employment, education and health indicators within the social sustainability context. The fundamental benefits from biogas production are considered and discussed with the technical issues surrounding biogas production also being presented. This is not just a technical unit for providing alternative energy supply, but it requires management, labour and knowledge, skills to operate on a daily basis for it to have an impact that can bring positive change to the daily social lives of both the young and old.
- Full Text:
- Date Issued: 2010
- Authors: Dhliwayo, Nyaradzo
- Date: 2010
- Subjects: Biogas -- Zimbabwe , Biogas -- Developing countries , Sustainability -- Zimbabwe
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:10648 , http://hdl.handle.net/10948/1459 , Biogas -- Zimbabwe , Biogas -- Developing countries , Sustainability -- Zimbabwe
- Description: The study has explored the social sustainability of biogas production in a local village of Sogwala which is located in the Lower Gweru District of Zimbabwe. The social sustainability assessment was based on the two concepts of social sustainability, namely human capital and social capital with particular emphasis on their respective elements and aspects. Qualitative and quantitative research methodology methods were used on a sample of 100 households using biogas and some key informants. Analysis of the variance was used to determine whether biogas production could account for any effects on the social and human capital elements of the Sogwala community. An overview and descriptive statistics analysis of the findings from the study have been provided where the biogas users’ experiences, perspectives are discussed and results were assessed. For instance, effects on the aspects of social capital elements which include increases in the social group membership of households after the introduction of biogas production the village; the performance of biogas energy as compared with other fuel sources in terms of accessibility, efficiency and the degree of labour needed for continual production of biogas. In view of the human capital element, assessment is done on the economic status per household before and after the production of biogas, where emphasis is placed on the aspects of employment, education and health indicators within the social sustainability context. The fundamental benefits from biogas production are considered and discussed with the technical issues surrounding biogas production also being presented. This is not just a technical unit for providing alternative energy supply, but it requires management, labour and knowledge, skills to operate on a daily basis for it to have an impact that can bring positive change to the daily social lives of both the young and old.
- Full Text:
- Date Issued: 2010
Spatial and seasonal distribution patterns of the ragged-tooth shark Carcharias taurus along the coast of South Africa
- Dicken, Matthew L, Booth, Anthony J, Smale, Malcolm J
- Authors: Dicken, Matthew L , Booth, Anthony J , Smale, Malcolm J
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/127008 , vital:35943 , https://doi.10.2989/18142320609504210
- Description: Off South Africa, the ragged-tooth shark Carcharias Taurus has been occasionally reported from the West Coast, but it is more commonly found along the East and South coasts from Cape Town to northern KwaZulu-Natal (KZN) (Bass et al. 1975, Smale 2002). Mating is thought to occur off the south coast of KZN from October to late November (G Cliff, Natal Sharks Board, unpublished data). Pregnant females then move northward to spend the early part of their gestation in the warmer waters of northern KZN and possibly southern Moçambique. During July and August, the near-term pregnant females begin to move southwards towards the cooler waters of the Eastern Cape (Wallett 1973, Bass et al. 1975, G Cliff, unpublished data), where they give birth from September to November (Smale 2002). After parturition, many of the females migrate back to KZN. The whereabouts of mature males outside of the mating season is unclear. These broadscale distribution and migratory habits for C. taurus have been inferred from limited catch records obtained for only parts of its range along the South African coast.
- Full Text:
- Date Issued: 2010
- Authors: Dicken, Matthew L , Booth, Anthony J , Smale, Malcolm J
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/127008 , vital:35943 , https://doi.10.2989/18142320609504210
- Description: Off South Africa, the ragged-tooth shark Carcharias Taurus has been occasionally reported from the West Coast, but it is more commonly found along the East and South coasts from Cape Town to northern KwaZulu-Natal (KZN) (Bass et al. 1975, Smale 2002). Mating is thought to occur off the south coast of KZN from October to late November (G Cliff, Natal Sharks Board, unpublished data). Pregnant females then move northward to spend the early part of their gestation in the warmer waters of northern KZN and possibly southern Moçambique. During July and August, the near-term pregnant females begin to move southwards towards the cooler waters of the Eastern Cape (Wallett 1973, Bass et al. 1975, G Cliff, unpublished data), where they give birth from September to November (Smale 2002). After parturition, many of the females migrate back to KZN. The whereabouts of mature males outside of the mating season is unclear. These broadscale distribution and migratory habits for C. taurus have been inferred from limited catch records obtained for only parts of its range along the South African coast.
- Full Text:
- Date Issued: 2010
Spatial and temporal patterns in the hyperbenthic community structure in a permanently open Eastern Cape estuary, South Africa
- Authors: Heyns, Elodie R
- Date: 2010
- Subjects: Sundays Estuary -- South Africa -- Eastern Cape , Groundfishes -- South Africa -- Eatern Cape , Estuaries -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5768 , http://hdl.handle.net/10962/d1005456
- Description: The spatial and temporal (seasonal and diel) patterns in the hyperbenthic community structure (>500 μm) was investigated in the warm temperate, permanently open Kariega Estuary situated along the south-eastern coastline of South Africa. Spatial and seasonal patterns in the hyperbenthic community structure were assessed monthly at six stations along the length of the estuary over a period of twelve months. Data were collected using a modified hyperbenthic sledge, comprising two super-imposed nets. Physico-chemical data indicate the presence of a constant reverse salinity gradient, with highest salinities measured in the upper reaches and lowest at the mouth of the estuary. Strong seasonal patterns in temperature, dissolved oxygen and total chlorophyll-a (chl-a) concentrations were evident. Total average hyperbenthic densities ranged between 0.04 and 166 ind.m-3 in the lower net and between 0.12 and 225 ind.m-3 in the upper net. Hyperbenthic biomass values ranged between 0.02 and 11.9 mg.dry weight.m-3 in the lower net and between 0.02 and 17.4 mg.dry weight.m-3 in the upper net. A spatial and temporal pattern in total densities was detected with an increase in abundance over the period of September to October 2008 particularly in the middle reaches (Stations 3 and 4). Both the lower and upper nets were numerically dominated by decapods (mainly brachyuran crab zoeae) with the exception of June and July 2008 when mysids (mainly Mesopodopsis wooldridgei) dominated, making up 72.4 ± 58.14% of the total abundance in the lower net. A redundancy analysis (RDA) indicated that 99.2% of the variance in the hyperbenthic community structure could be explained by the first two canonical axes. Axis one, which accounted for 96.8% of the total variation detected in the ordination plot was highly correlated with sedimentary organic content and to a lesser extent the chl-a concentration within the Kariega Estuary. The correlations with the second canonical axis (2.4%) were less obvious, however, salinity and seston concentration were weakly correlated with this axis. Diel variability in the hyperbenthic community structure was assessed during March 2009. Samples were collected during the day and night (n = 6 for each period) using sampling gear described above. Total average hyperbenthic densities during the day (497.9 ± 254.1 ind.m-3) were significantly higher than night-time estimates (129.9 ± 38.5 ind.m-3; p<0.05). There were no significant differences in the average dayand night-time estimates of hyperbenthic biomass (p>0.05). A hierarchical cluster analysis identified two significantly distinct groupings, designated the day and night samples. Results from the SIMPER procedure indicated that the high densities of crab zoeae recorded during the day-time accounted for the majority of the dissimilarity between the day and night groupings (44.7%). In addition, it is apparent that several benthic species, especially from the cumacean and isopod orders, were absent from the hyperbenthos during the day-time and emerged into the water column at night.
- Full Text:
- Date Issued: 2010
- Authors: Heyns, Elodie R
- Date: 2010
- Subjects: Sundays Estuary -- South Africa -- Eastern Cape , Groundfishes -- South Africa -- Eatern Cape , Estuaries -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5768 , http://hdl.handle.net/10962/d1005456
- Description: The spatial and temporal (seasonal and diel) patterns in the hyperbenthic community structure (>500 μm) was investigated in the warm temperate, permanently open Kariega Estuary situated along the south-eastern coastline of South Africa. Spatial and seasonal patterns in the hyperbenthic community structure were assessed monthly at six stations along the length of the estuary over a period of twelve months. Data were collected using a modified hyperbenthic sledge, comprising two super-imposed nets. Physico-chemical data indicate the presence of a constant reverse salinity gradient, with highest salinities measured in the upper reaches and lowest at the mouth of the estuary. Strong seasonal patterns in temperature, dissolved oxygen and total chlorophyll-a (chl-a) concentrations were evident. Total average hyperbenthic densities ranged between 0.04 and 166 ind.m-3 in the lower net and between 0.12 and 225 ind.m-3 in the upper net. Hyperbenthic biomass values ranged between 0.02 and 11.9 mg.dry weight.m-3 in the lower net and between 0.02 and 17.4 mg.dry weight.m-3 in the upper net. A spatial and temporal pattern in total densities was detected with an increase in abundance over the period of September to October 2008 particularly in the middle reaches (Stations 3 and 4). Both the lower and upper nets were numerically dominated by decapods (mainly brachyuran crab zoeae) with the exception of June and July 2008 when mysids (mainly Mesopodopsis wooldridgei) dominated, making up 72.4 ± 58.14% of the total abundance in the lower net. A redundancy analysis (RDA) indicated that 99.2% of the variance in the hyperbenthic community structure could be explained by the first two canonical axes. Axis one, which accounted for 96.8% of the total variation detected in the ordination plot was highly correlated with sedimentary organic content and to a lesser extent the chl-a concentration within the Kariega Estuary. The correlations with the second canonical axis (2.4%) were less obvious, however, salinity and seston concentration were weakly correlated with this axis. Diel variability in the hyperbenthic community structure was assessed during March 2009. Samples were collected during the day and night (n = 6 for each period) using sampling gear described above. Total average hyperbenthic densities during the day (497.9 ± 254.1 ind.m-3) were significantly higher than night-time estimates (129.9 ± 38.5 ind.m-3; p<0.05). There were no significant differences in the average dayand night-time estimates of hyperbenthic biomass (p>0.05). A hierarchical cluster analysis identified two significantly distinct groupings, designated the day and night samples. Results from the SIMPER procedure indicated that the high densities of crab zoeae recorded during the day-time accounted for the majority of the dissimilarity between the day and night groupings (44.7%). In addition, it is apparent that several benthic species, especially from the cumacean and isopod orders, were absent from the hyperbenthos during the day-time and emerged into the water column at night.
- Full Text:
- Date Issued: 2010
Spatial description of hake-directed fishing activity off the west coast of South Africa
- Fairweather, T P, Booth, Anthony J, Sauer, Warwick H H, Leslie, Rob W
- Authors: Fairweather, T P , Booth, Anthony J , Sauer, Warwick H H , Leslie, Rob W
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/127031 , vital:35945 , https://doi.10.2989/18142320609504129
- Description: Historically, the two species of Cape hakes Merluccius capensis and M. paradoxus off South Africa were commercially exploited exclusively by demersal trawling. In 1994, hake-directed demersal longline was introduced on an experimental basis, and in 1998 was initiated as a commercial fishing sector. The effect of a combined fleet composed of both trawlers and longliners on the Cape hake resource is not fully understood. Analysis of fishing intensity and catch-rate data revealed that the highest catch rates were found around the 400m and 500m isobaths for the trawl and longline fisheries respectively. Catch rates from both fishing sectors were also noted to be higher over sediments with a sand component. Differences between areas of the highest fishing intensity and highest catch rates were noted. In addition to other factors, it is suggested that a ‘friction of distance’ effect applies — vessels will trade-off higher catch rates with the increased costs associated with fishing in deeper waters.
- Full Text:
- Date Issued: 2010
- Authors: Fairweather, T P , Booth, Anthony J , Sauer, Warwick H H , Leslie, Rob W
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/127031 , vital:35945 , https://doi.10.2989/18142320609504129
- Description: Historically, the two species of Cape hakes Merluccius capensis and M. paradoxus off South Africa were commercially exploited exclusively by demersal trawling. In 1994, hake-directed demersal longline was introduced on an experimental basis, and in 1998 was initiated as a commercial fishing sector. The effect of a combined fleet composed of both trawlers and longliners on the Cape hake resource is not fully understood. Analysis of fishing intensity and catch-rate data revealed that the highest catch rates were found around the 400m and 500m isobaths for the trawl and longline fisheries respectively. Catch rates from both fishing sectors were also noted to be higher over sediments with a sand component. Differences between areas of the highest fishing intensity and highest catch rates were noted. In addition to other factors, it is suggested that a ‘friction of distance’ effect applies — vessels will trade-off higher catch rates with the increased costs associated with fishing in deeper waters.
- Full Text:
- Date Issued: 2010
Spatially resolved opto-electric measurements of photovoltaic materials and devices
- Authors: Thantsha, Nicolas Matome
- Date: 2010
- Subjects: Photovoltaic cells , Photovoltaic power systems , Photovoltaic power generation
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10520 , http://hdl.handle.net/10948/1123 , Photovoltaic cells , Photovoltaic power systems , Photovoltaic power generation
- Description: The objective of this study is to characterize and analyse defects in solar cell devices. Materials used to fabricate solar cells are not defects free and therefore, there is a need to investigate defects in cells. To investigate this, a topographical technique was developed and employed which uses a non-destructive methodology to analyse solar cells. A system was built which uses a technique based on a laser beam induced current (LBIC). LBIC technique involves focusing light on to a surface of a solar cell device in order to create a photo-generated current that can be measured in the external circuit for analyses. The advantage of this technique is that it allows parameter extraction. Parameters that can be extracted include short-circuit current, carrier lifetime and also the external and internal quantum efficiency of a solar cell. In this thesis, LBIC measurements in the form of picture maps are used to indicate the distribution of the localized beam induced current within solar cells. Areas with low minority carrier lifetime in solar cells are made visible by LBIC mapping. Surface reflection intensity measurements of cells can also be mapped using the LBIC system developed in this study. The system is also capable of mapping photo-generated current of a cell below and above room temperature. This thesis also presents an assessment procedure capable of assessing the device and performance parameters with reference to I-V measurements. The dark and illuminated I-V characteristics of solar cells were investigated. The illuminated I-V characteristics of solar cells were obtained using a defocused laser beam. Dark I-V measurements were performed by applying voltage across the cell in the dark and measuring a current through it. The device parameters which describe the behaviour of I-V characteristic were extracted from the I-V data using Particle Swarm Optimization (PSO) method based on a one-and two-diode solar cell models. Solar cells of different technologies were analysed, namely, single-crystalline (c-Si) and multicrystalline (mc-Si) silicon, Edge-defined Film-fed Growth Si (EFG-Si) and Cu(In,Ga)(Se,S)2 (CIGSS) thin film based cells. The LBIC results illustrated the effect of surface reflection features and material defects in the solar cell investigated. IQE at a wavelength of 660 nm were measured on these cells and the results in general emphasised the importance of correcting optical losses, i.e. reflection loss, when characterizing different types of defects. The agreement between the IQE measurements and I-V characteristics of a cell showed that the differences in crystal grains influence the performance of a mc-Si cell. The temperature-dependence of I-V characteristics of a CIGSS solar cell was investigated. The results showed that, for this material, the photo response is reduced at elevated temperatures. In addition to LBIC using a laser beam, solar spectral radiation was employed to obtained device performance parameters. The results emphasised the effect of grain boundaries as a recombination centres for photo-generated hole-pairs. Lastly, mesa diode characterizations of solar cells were investigated. Mesa diodes are achieved by etching down a solar cell so that the plateau regions are formed. Mesa diodes expose the p-n junction, and therefore mesa diode analysis provides a better way of determining and revealing the fundamental current conduction mechanism at the junction. Mesa diodes avoid possible edge effects. This study showed that mesa diodes can be used to characterize spatial non-uniformities in solar cells. The results obtained in this study indicate that LBIC is a useful tool for defect characterization in solar cells. Also LBIC complements other characterization techniques such as I-V characterization.
- Full Text:
- Date Issued: 2010
- Authors: Thantsha, Nicolas Matome
- Date: 2010
- Subjects: Photovoltaic cells , Photovoltaic power systems , Photovoltaic power generation
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10520 , http://hdl.handle.net/10948/1123 , Photovoltaic cells , Photovoltaic power systems , Photovoltaic power generation
- Description: The objective of this study is to characterize and analyse defects in solar cell devices. Materials used to fabricate solar cells are not defects free and therefore, there is a need to investigate defects in cells. To investigate this, a topographical technique was developed and employed which uses a non-destructive methodology to analyse solar cells. A system was built which uses a technique based on a laser beam induced current (LBIC). LBIC technique involves focusing light on to a surface of a solar cell device in order to create a photo-generated current that can be measured in the external circuit for analyses. The advantage of this technique is that it allows parameter extraction. Parameters that can be extracted include short-circuit current, carrier lifetime and also the external and internal quantum efficiency of a solar cell. In this thesis, LBIC measurements in the form of picture maps are used to indicate the distribution of the localized beam induced current within solar cells. Areas with low minority carrier lifetime in solar cells are made visible by LBIC mapping. Surface reflection intensity measurements of cells can also be mapped using the LBIC system developed in this study. The system is also capable of mapping photo-generated current of a cell below and above room temperature. This thesis also presents an assessment procedure capable of assessing the device and performance parameters with reference to I-V measurements. The dark and illuminated I-V characteristics of solar cells were investigated. The illuminated I-V characteristics of solar cells were obtained using a defocused laser beam. Dark I-V measurements were performed by applying voltage across the cell in the dark and measuring a current through it. The device parameters which describe the behaviour of I-V characteristic were extracted from the I-V data using Particle Swarm Optimization (PSO) method based on a one-and two-diode solar cell models. Solar cells of different technologies were analysed, namely, single-crystalline (c-Si) and multicrystalline (mc-Si) silicon, Edge-defined Film-fed Growth Si (EFG-Si) and Cu(In,Ga)(Se,S)2 (CIGSS) thin film based cells. The LBIC results illustrated the effect of surface reflection features and material defects in the solar cell investigated. IQE at a wavelength of 660 nm were measured on these cells and the results in general emphasised the importance of correcting optical losses, i.e. reflection loss, when characterizing different types of defects. The agreement between the IQE measurements and I-V characteristics of a cell showed that the differences in crystal grains influence the performance of a mc-Si cell. The temperature-dependence of I-V characteristics of a CIGSS solar cell was investigated. The results showed that, for this material, the photo response is reduced at elevated temperatures. In addition to LBIC using a laser beam, solar spectral radiation was employed to obtained device performance parameters. The results emphasised the effect of grain boundaries as a recombination centres for photo-generated hole-pairs. Lastly, mesa diode characterizations of solar cells were investigated. Mesa diodes are achieved by etching down a solar cell so that the plateau regions are formed. Mesa diodes expose the p-n junction, and therefore mesa diode analysis provides a better way of determining and revealing the fundamental current conduction mechanism at the junction. Mesa diodes avoid possible edge effects. This study showed that mesa diodes can be used to characterize spatial non-uniformities in solar cells. The results obtained in this study indicate that LBIC is a useful tool for defect characterization in solar cells. Also LBIC complements other characterization techniques such as I-V characterization.
- Full Text:
- Date Issued: 2010
Spatio-temporal dynamics of ichthyoplankton in the Kowie estuary, South Africa
- Authors: Kruger, Michelle
- Date: 2010
- Subjects: Fishes -- Larvae -- South Africa -- Port Alfred , Estuarine fishes -- South Africa -- Port Alfred
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5319 , http://hdl.handle.net/10962/d1005164 , Fishes -- Larvae -- South Africa -- Port Alfred , Estuarine fishes -- South Africa -- Port Alfred
- Description: Ichthyoplankton dynamics in the permanently open Kowie Estuary, in the warm temperate region of South Africa was investigated. The composition, abundance, distribution and seasonality of larval fishes were studied over a two year period between 2004 and 2006. Additionally, tidal exchange of ichthyoplankton and the use of frontal zones in the mouth region of the estuary were also explored between 2008 and 2009. Temporal and spatial trends in occurrence of larval fishes within the estuary and associated marina were obtained from data collected seasonally using boat-based plankton netting at 14 sampling stations along the length of the estuary. A total of 11 128 larval fishes were collected, representing 23 families and 38 taxa. Clupeidae and Gobiidae were the dominant fish families, contributing 47.0 % and 24.7 % respectively to the total catch. Estuarine resident species dominated the overall catch (91 %). A notable absence of older stage larvae and early juveniles characterised the artificial channels of the marina and estuary mouth region. This was attributed to the absence of a shallow, marginal water habitat typical of successful estuarine nursery areas. Tidal exchange of larval fishes was investigated in the Kowie Estuary using a new technique. A set of drifting light traps were set repetitively on the ebb and flood tide every second night for two consecutive 14 day periods during the peak estuarine recruitment period. A total of 553 larval fishes were caught during the study, representing nine families and 26 species. Blenniidae and Clupeidae dominated the catches. Family and species occurrence changed with tide state. Species richness (d) and diversity (H’) varied with tide and was highest on flood tides. Estuary-dependent species, such as Omobranchus woodii were more dominant on flood tides, whilst larvae of marine-spawned species, such as Sardinops sagax, were dominant on the ebb tide. Light trap catches yielded a different composition in terms of development stage / size and species, when compared to towed net studies. Towed plankton nets were again used to study the shear fronts that characterise the mouth region of the canalised Kowie Estuary. It was hypothesised that the convergence zone of the front provides feeding opportunities for ichthyoplankton. Ichthyoplankton, zooplankton and phytoplankton was collected from within and immediately outside of the convergence zone during frontal conditions. Species specific distribution trends emerged from this study. Postflexion larvae and early juvenile stages of the estuary dependent Mugilidae were only present in the foam line of the convergence zones. Some known predators of ichthyoplankton were also present in slightly higher numbers in the convergence zone (isopods) while other predators such as mysid shrimps, chaetognaths and cnidarians were more abundant out of the convergence zone. It appears that these zones may provide access to temporary food patches in the lower estuary but will be accompanied by a trade-off with increased isopod predators. The Kowie Estuary is a heavily impacted system and lack of adequate freshwater supply; artificial channelling and pollution ultimately have a negative impact of the success of this system as a nursery area. Rehabilitation of marginal areas in the lower estuary and marina is suggested as remedial action to re-establish the integrity of the nursery function this system could offer.
- Full Text:
- Date Issued: 2010
- Authors: Kruger, Michelle
- Date: 2010
- Subjects: Fishes -- Larvae -- South Africa -- Port Alfred , Estuarine fishes -- South Africa -- Port Alfred
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5319 , http://hdl.handle.net/10962/d1005164 , Fishes -- Larvae -- South Africa -- Port Alfred , Estuarine fishes -- South Africa -- Port Alfred
- Description: Ichthyoplankton dynamics in the permanently open Kowie Estuary, in the warm temperate region of South Africa was investigated. The composition, abundance, distribution and seasonality of larval fishes were studied over a two year period between 2004 and 2006. Additionally, tidal exchange of ichthyoplankton and the use of frontal zones in the mouth region of the estuary were also explored between 2008 and 2009. Temporal and spatial trends in occurrence of larval fishes within the estuary and associated marina were obtained from data collected seasonally using boat-based plankton netting at 14 sampling stations along the length of the estuary. A total of 11 128 larval fishes were collected, representing 23 families and 38 taxa. Clupeidae and Gobiidae were the dominant fish families, contributing 47.0 % and 24.7 % respectively to the total catch. Estuarine resident species dominated the overall catch (91 %). A notable absence of older stage larvae and early juveniles characterised the artificial channels of the marina and estuary mouth region. This was attributed to the absence of a shallow, marginal water habitat typical of successful estuarine nursery areas. Tidal exchange of larval fishes was investigated in the Kowie Estuary using a new technique. A set of drifting light traps were set repetitively on the ebb and flood tide every second night for two consecutive 14 day periods during the peak estuarine recruitment period. A total of 553 larval fishes were caught during the study, representing nine families and 26 species. Blenniidae and Clupeidae dominated the catches. Family and species occurrence changed with tide state. Species richness (d) and diversity (H’) varied with tide and was highest on flood tides. Estuary-dependent species, such as Omobranchus woodii were more dominant on flood tides, whilst larvae of marine-spawned species, such as Sardinops sagax, were dominant on the ebb tide. Light trap catches yielded a different composition in terms of development stage / size and species, when compared to towed net studies. Towed plankton nets were again used to study the shear fronts that characterise the mouth region of the canalised Kowie Estuary. It was hypothesised that the convergence zone of the front provides feeding opportunities for ichthyoplankton. Ichthyoplankton, zooplankton and phytoplankton was collected from within and immediately outside of the convergence zone during frontal conditions. Species specific distribution trends emerged from this study. Postflexion larvae and early juvenile stages of the estuary dependent Mugilidae were only present in the foam line of the convergence zones. Some known predators of ichthyoplankton were also present in slightly higher numbers in the convergence zone (isopods) while other predators such as mysid shrimps, chaetognaths and cnidarians were more abundant out of the convergence zone. It appears that these zones may provide access to temporary food patches in the lower estuary but will be accompanied by a trade-off with increased isopod predators. The Kowie Estuary is a heavily impacted system and lack of adequate freshwater supply; artificial channelling and pollution ultimately have a negative impact of the success of this system as a nursery area. Rehabilitation of marginal areas in the lower estuary and marina is suggested as remedial action to re-establish the integrity of the nursery function this system could offer.
- Full Text:
- Date Issued: 2010
Spectroscopic behavior of cationic metallophthalocyanines in the presence of anionic quantum dots
- Idowu, Mopelola A I, Nyokong, Tebello
- Authors: Idowu, Mopelola A I , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/262699 , vital:53545 , xlink:href="https://doi.org/10.1016/j.saa.2009.10.050"
- Description: The interactions and spectroscopic properties between cationic zinc phthalocyanine derivatives (peripherally and non-peripherally tetrasubstituted and peripherally octa substituted with 2-diethylmethylaminoethylsulfanyl (βTZnPc, αTZnPc and βOZnPc)) and CdTe core quantum dots (QDs) capped with mercaptopropionic acid or thioglycolic acid (represented as CdTe@MPA and CdTe@TGA, respectively) have been studied in methanol:water mixture. Strong coupling of MPcs was deduced from the interaction since the UV–vis spectroscopic studies of the ground state complex formed on mixing both components showed loss of the phthalocyanine monomeric band with the formation of a dimeric band (spectrum of aggregated species). The dimerization constants were of the order of 104 M−1.
- Full Text:
- Date Issued: 2010
- Authors: Idowu, Mopelola A I , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/262699 , vital:53545 , xlink:href="https://doi.org/10.1016/j.saa.2009.10.050"
- Description: The interactions and spectroscopic properties between cationic zinc phthalocyanine derivatives (peripherally and non-peripherally tetrasubstituted and peripherally octa substituted with 2-diethylmethylaminoethylsulfanyl (βTZnPc, αTZnPc and βOZnPc)) and CdTe core quantum dots (QDs) capped with mercaptopropionic acid or thioglycolic acid (represented as CdTe@MPA and CdTe@TGA, respectively) have been studied in methanol:water mixture. Strong coupling of MPcs was deduced from the interaction since the UV–vis spectroscopic studies of the ground state complex formed on mixing both components showed loss of the phthalocyanine monomeric band with the formation of a dimeric band (spectrum of aggregated species). The dimerization constants were of the order of 104 M−1.
- Full Text:
- Date Issued: 2010