The accelerated life cycle testing and modelling of Li-ion cells used in electric vehicle applications
- Authors: Rossouw, Claire Angela
- Date: 2012
- Subjects: Lithium Ions , Electric batteries , Energy storage , Electric vehicles -- Power supply
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:10417 , http://hdl.handle.net/10948/d1012709 , Lithium Ions , Electric batteries , Energy storage , Electric vehicles -- Power supply
- Description: Li-ion batteries have become one of the chosen energy storage devices that are used in applications such as power tools, cellular phones and electric vehicles (EV). With the demand for portable high energy density devices, the rechargeable Li-ion battery has become one of the more viable energy storage systems for large scale commercial EVs because of their higher energy density to weight or volume ratio when compared to other current commercial battery energy storage systems. Various safety procedures for the use of Li-ion batteries in both consumer and EV applications have been developed by the international associations. The test procedures studied in this dissertation demonstrated the importance of determining the true capacity of a cell at various discharge rates. For this, the well known Peukert test was demonstrated. The study also showed that cells with different battery geometries and chemistries would demonstrate different thermal heating during discharge and slightly different Ragone results if different test methods were used as reported in the literature. Accelerated ageing tests were done on different cells at different Depth-of-Discharge (DoD) regions. The different DoD regions were determined according to expected stresses the electrode material in a cell would experience when discharged to specific DoD that follows the discharge voltage profile. Electrochemical Impedance Spectroscopy (EIS) was used to measure various electrochemical changes within these cells. The EIS results showed that certain observed modelled parameters would change similarly to the ageing of the cell as it aged due to the accelerated testing. EIS was also done on cells at different State-of-Charge (SoC) and temperatures. The results showed that EIS can be used as an effective technique to observe changes within a Li-ion cell as the SoC or temperature changed. For automotive vehicles that are powered by a fuel cell or battery, a supercapacitor can be coupled to a battery in order to increase and optimize the energy and power densities of the drive systems. A test procedure in the literature that evaluated the use of capacitors with Pb-acid batteries was applied to Li-ion type cells in order to quantify the increased power due to the use of a supercapacitor with a Li-ion cell. Both a cylindrical LiCoO2 cell and a VRLA Pb-acid cell showed some additional charge acceptance and delivery when connected to the supercapacitors. A LiMn2O4 pouch cell showed significant charge acceptance and delivery when connected to supercapacitors. The amount of additional charge acceptance and delivery of the different combinations could be explained by EIS, in particular, the resistance and capacitance of the cell in comparison to the combination of the cell and supercapacitor. A large capacity LiCoO2 cell showed high charge acceptance and delivery without connection with a supercapacitor. The study proved that EIS can be used to model the changes within cells under the different conditions and using different test procedures.
- Full Text:
- Date Issued: 2012
- Authors: Rossouw, Claire Angela
- Date: 2012
- Subjects: Lithium Ions , Electric batteries , Energy storage , Electric vehicles -- Power supply
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:10417 , http://hdl.handle.net/10948/d1012709 , Lithium Ions , Electric batteries , Energy storage , Electric vehicles -- Power supply
- Description: Li-ion batteries have become one of the chosen energy storage devices that are used in applications such as power tools, cellular phones and electric vehicles (EV). With the demand for portable high energy density devices, the rechargeable Li-ion battery has become one of the more viable energy storage systems for large scale commercial EVs because of their higher energy density to weight or volume ratio when compared to other current commercial battery energy storage systems. Various safety procedures for the use of Li-ion batteries in both consumer and EV applications have been developed by the international associations. The test procedures studied in this dissertation demonstrated the importance of determining the true capacity of a cell at various discharge rates. For this, the well known Peukert test was demonstrated. The study also showed that cells with different battery geometries and chemistries would demonstrate different thermal heating during discharge and slightly different Ragone results if different test methods were used as reported in the literature. Accelerated ageing tests were done on different cells at different Depth-of-Discharge (DoD) regions. The different DoD regions were determined according to expected stresses the electrode material in a cell would experience when discharged to specific DoD that follows the discharge voltage profile. Electrochemical Impedance Spectroscopy (EIS) was used to measure various electrochemical changes within these cells. The EIS results showed that certain observed modelled parameters would change similarly to the ageing of the cell as it aged due to the accelerated testing. EIS was also done on cells at different State-of-Charge (SoC) and temperatures. The results showed that EIS can be used as an effective technique to observe changes within a Li-ion cell as the SoC or temperature changed. For automotive vehicles that are powered by a fuel cell or battery, a supercapacitor can be coupled to a battery in order to increase and optimize the energy and power densities of the drive systems. A test procedure in the literature that evaluated the use of capacitors with Pb-acid batteries was applied to Li-ion type cells in order to quantify the increased power due to the use of a supercapacitor with a Li-ion cell. Both a cylindrical LiCoO2 cell and a VRLA Pb-acid cell showed some additional charge acceptance and delivery when connected to the supercapacitors. A LiMn2O4 pouch cell showed significant charge acceptance and delivery when connected to supercapacitors. The amount of additional charge acceptance and delivery of the different combinations could be explained by EIS, in particular, the resistance and capacitance of the cell in comparison to the combination of the cell and supercapacitor. A large capacity LiCoO2 cell showed high charge acceptance and delivery without connection with a supercapacitor. The study proved that EIS can be used to model the changes within cells under the different conditions and using different test procedures.
- Full Text:
- Date Issued: 2012
Analysis of fuel consumption reduction potential through the use of an electrically driven air conditioning compressor
- Authors: Marais, Charel
- Date: 2007
- Subjects: Automobiles -- Air conditioning , Electric vehicles -- Power supply , Automobiles -- Fuel systems , Electric automobiles
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:9623 , http://hdl.handle.net/10948/774 , Automobiles -- Air conditioning , Electric vehicles -- Power supply , Automobiles -- Fuel systems , Electric automobiles
- Description: The disturbing current situation regarding the world climate has initiated a major wave of urgent developments towards decreasing the overall impact of human activities on the living environment. A major role player in this development is the automobile industry that is inherently connected to pollution of various types, be it air, water or noise pollution. There have been drastic changes not only in the technologies employed in producing vehicles and components, but also in the construction and technologies built into modern automobiles to lessen the overall environmental impact of the industry. Noxious emissions have been decreased, overall efficiencies increased and vehicles are becoming more economical with each new generation. Stricter laws dictate that the level of acceptable vehicle emissions is to be decreased ever further and all manufacturers are developing various possibilities to achieve this. With the emergence of hybrid vehicle technology, there was also a sudden development of different electrical systems that were made viable by the higher onboard voltage systems employed in hybrid vehicles. One of these developments was the electrical air conditioning compressor for use in automobile applications. Although it is designed to operate with a higher voltage than the traditional 12V onboard vehicle systems, it is theoretically possible to incorporate it into a 12V system by making use of a DC-DC converter to step up the supply voltage of the electrical compressor sufficiently to allow for its successful operation. The question therefore arises whether it would be feasible and sensible to employ an electrical air conditioning system in conventional combustion engine vehicles from an overall fuel consumption and vehicle emissions point of view. A modelling approach was taken where an overall vehicle driving simulation was created to represent an average modern production vehicle. The simulation was then extended to include the options of incorporating models for both mechanically and electrically driven air conditioning systems. This provides insight into the influences of the air conditioning system on the vehicle’s overall fuel consumption and an opportunity to compare the influences from the two different systems. This study attempted to provide answers to some of the viability questions regarding the incorporation of electrically driven air conditioning systems into vehicles that use standard 12V onboard voltage systems. It was found that the electrical system has definite potential as a viable replacement option for the conventional system should it be combined with an appropriate alternator and equipped with an efficient control system.
- Full Text:
- Date Issued: 2007
- Authors: Marais, Charel
- Date: 2007
- Subjects: Automobiles -- Air conditioning , Electric vehicles -- Power supply , Automobiles -- Fuel systems , Electric automobiles
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:9623 , http://hdl.handle.net/10948/774 , Automobiles -- Air conditioning , Electric vehicles -- Power supply , Automobiles -- Fuel systems , Electric automobiles
- Description: The disturbing current situation regarding the world climate has initiated a major wave of urgent developments towards decreasing the overall impact of human activities on the living environment. A major role player in this development is the automobile industry that is inherently connected to pollution of various types, be it air, water or noise pollution. There have been drastic changes not only in the technologies employed in producing vehicles and components, but also in the construction and technologies built into modern automobiles to lessen the overall environmental impact of the industry. Noxious emissions have been decreased, overall efficiencies increased and vehicles are becoming more economical with each new generation. Stricter laws dictate that the level of acceptable vehicle emissions is to be decreased ever further and all manufacturers are developing various possibilities to achieve this. With the emergence of hybrid vehicle technology, there was also a sudden development of different electrical systems that were made viable by the higher onboard voltage systems employed in hybrid vehicles. One of these developments was the electrical air conditioning compressor for use in automobile applications. Although it is designed to operate with a higher voltage than the traditional 12V onboard vehicle systems, it is theoretically possible to incorporate it into a 12V system by making use of a DC-DC converter to step up the supply voltage of the electrical compressor sufficiently to allow for its successful operation. The question therefore arises whether it would be feasible and sensible to employ an electrical air conditioning system in conventional combustion engine vehicles from an overall fuel consumption and vehicle emissions point of view. A modelling approach was taken where an overall vehicle driving simulation was created to represent an average modern production vehicle. The simulation was then extended to include the options of incorporating models for both mechanically and electrically driven air conditioning systems. This provides insight into the influences of the air conditioning system on the vehicle’s overall fuel consumption and an opportunity to compare the influences from the two different systems. This study attempted to provide answers to some of the viability questions regarding the incorporation of electrically driven air conditioning systems into vehicles that use standard 12V onboard voltage systems. It was found that the electrical system has definite potential as a viable replacement option for the conventional system should it be combined with an appropriate alternator and equipped with an efficient control system.
- Full Text:
- Date Issued: 2007
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