Perceptions of small-scale vegetable farmers on drought mitigation strategies in the Amathole District Municipality of the Eastern Cape Province
- Authors: Dingiswayo, Xolisile
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/53676 , vital:45686
- Description: The present study aimed to investigate perceptions of small-scale vegetable farmers on drought mitigation strategies in the Amathole District Municipality of the Eastern Cape Province. The research objective was to investigate what small-scale vegetable farmers’ perceptions and readiness are in terms of strategies to cope with drought conditions. The study was conducted within the Mbashe, Mnquma, Amahlathi and Great Kei local municipalities of the Eastern Cape. Primary data collection was conducted among 44 small-scale vegetable farmers of the Amathole municipal district. These are farmers who receive social support from the government, are registered with the Department of Rural Development and Agrarian Reform and contribute to the fight against food insecurity in the Amathole district. The primary data was also collected from 13 agricultural extension officers with high experience in advising small-scale farmers residing in the Amathole district. Data collection took place in various local municipalities under Amathole District Municipality, namely: Mbashe, Mnquma, Amahlathi and Great Kei. A multi-method approach was adopted in this study as an appropriate technique to create an improved quality of research which eliminates the deep-rooted bias to either qualitative or quantitative methods alone. A self-administered questionnaires with both closed and open-ended questions – one for the small-scale farmer survey and the second for the extension officer survey – was employed as data collection instrument. The demographic characteristics of small-scale vegetable farmers in the survey area indicated that the present majority of farmers are married male Xhosa farmers between the ages of 56 and 65 years old, with a secondary level of education. The majority of the farmers are typically resource-poor − which implies that the added menace of drought poses the risk that small-scale vegetable farming could decline to mere subsistence level or worse. Drought was found to be a major problem in Mbashe, Mnquma, Amahlathi and Great Kei local municipalities within the Amathole municipal district, with an acute impact on farmers’ production and generation of income. From the data, it emerged that farmers are not sufficiently informed about and do not receive specific training in drought mitigation strategies. Farmers rely on drought alleviation methods but there is a lack of adaptive strategies and timely, long-term ii state intervention. Being resource-poor, these small-scale producers are reliant on natural resources – notably water for irrigating crops. The study established further that there is neither the resources nor sufficient training by and involvement of the extension service. Farmers therefore rely on the use of drought coping mechanisms and drought mitigation techniques and on adapting their production systems. The information-sharing sessions recommended can assist in improving rural livelihoods and the productivity of small-scale vegetable farmers. The absence of engagement of youth in farming means that modern conservation and innovative farming techniques and systems are not implemented towards reducing the impacts of climate change − as well as revitalizing rural areas such Amathole. Access to education about drought, improved drought coping mechanisms and adaptive strategies should be created to facilitate an exchange of traditional and modern agricultural information. The development of infrastructure in rural communities and farming areas is another factor crucial to improving farming systems and operations in the Amathole municipal district. , Thesis (MSc) -- Faculty of Science, School of Natural Resource Management, 2021
- Full Text: false
- Date Issued: 2021-12
- Authors: Dingiswayo, Xolisile
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/53676 , vital:45686
- Description: The present study aimed to investigate perceptions of small-scale vegetable farmers on drought mitigation strategies in the Amathole District Municipality of the Eastern Cape Province. The research objective was to investigate what small-scale vegetable farmers’ perceptions and readiness are in terms of strategies to cope with drought conditions. The study was conducted within the Mbashe, Mnquma, Amahlathi and Great Kei local municipalities of the Eastern Cape. Primary data collection was conducted among 44 small-scale vegetable farmers of the Amathole municipal district. These are farmers who receive social support from the government, are registered with the Department of Rural Development and Agrarian Reform and contribute to the fight against food insecurity in the Amathole district. The primary data was also collected from 13 agricultural extension officers with high experience in advising small-scale farmers residing in the Amathole district. Data collection took place in various local municipalities under Amathole District Municipality, namely: Mbashe, Mnquma, Amahlathi and Great Kei. A multi-method approach was adopted in this study as an appropriate technique to create an improved quality of research which eliminates the deep-rooted bias to either qualitative or quantitative methods alone. A self-administered questionnaires with both closed and open-ended questions – one for the small-scale farmer survey and the second for the extension officer survey – was employed as data collection instrument. The demographic characteristics of small-scale vegetable farmers in the survey area indicated that the present majority of farmers are married male Xhosa farmers between the ages of 56 and 65 years old, with a secondary level of education. The majority of the farmers are typically resource-poor − which implies that the added menace of drought poses the risk that small-scale vegetable farming could decline to mere subsistence level or worse. Drought was found to be a major problem in Mbashe, Mnquma, Amahlathi and Great Kei local municipalities within the Amathole municipal district, with an acute impact on farmers’ production and generation of income. From the data, it emerged that farmers are not sufficiently informed about and do not receive specific training in drought mitigation strategies. Farmers rely on drought alleviation methods but there is a lack of adaptive strategies and timely, long-term ii state intervention. Being resource-poor, these small-scale producers are reliant on natural resources – notably water for irrigating crops. The study established further that there is neither the resources nor sufficient training by and involvement of the extension service. Farmers therefore rely on the use of drought coping mechanisms and drought mitigation techniques and on adapting their production systems. The information-sharing sessions recommended can assist in improving rural livelihoods and the productivity of small-scale vegetable farmers. The absence of engagement of youth in farming means that modern conservation and innovative farming techniques and systems are not implemented towards reducing the impacts of climate change − as well as revitalizing rural areas such Amathole. Access to education about drought, improved drought coping mechanisms and adaptive strategies should be created to facilitate an exchange of traditional and modern agricultural information. The development of infrastructure in rural communities and farming areas is another factor crucial to improving farming systems and operations in the Amathole municipal district. , Thesis (MSc) -- Faculty of Science, School of Natural Resource Management, 2021
- Full Text: false
- Date Issued: 2021-12
Plastic particle characterization and concentrations found in the river and marine water environment of Algoa Bay, South Africa
- Authors: Moss, Kerry-Leigh
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/53874 , vital:46025
- Description: Only 12% of the world's published plastic research includes references to Africa despite it being a significant contributor to the global plastic waste and mismanagement problem (~88.5% of Africa's plastic waste is mismanaged). Ocean plastics are transported from land by rivers to the sea. However, source contextualization is complex. Many African rivers predominantly run alongside human settlements that host informal waste dumpsites. In this study a simple cost effective, easily deployed, consistent and replicable survey methodology was employed. The study quantified macro plastic in three rivers discharging into Algoa Bay, South Africa. The results indicated that industrial Swartkops and metropolitan Baakens Rivers both illustrate moderate plastic pollution (>3000 plastic particles/day), with the relatively natural Sundays River to showing minimal evidence of river macroplastic (<100 plastic particles/day). The types of plastic were noted using the RIMMEL app (premier African implementation), enabling proportional comparison of different plastic litter types to be completed. , Thesis (MSc) -- Faculty of Science, Oceanography Department,2021
- Full Text:
- Date Issued: 2021-12
- Authors: Moss, Kerry-Leigh
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/53874 , vital:46025
- Description: Only 12% of the world's published plastic research includes references to Africa despite it being a significant contributor to the global plastic waste and mismanagement problem (~88.5% of Africa's plastic waste is mismanaged). Ocean plastics are transported from land by rivers to the sea. However, source contextualization is complex. Many African rivers predominantly run alongside human settlements that host informal waste dumpsites. In this study a simple cost effective, easily deployed, consistent and replicable survey methodology was employed. The study quantified macro plastic in three rivers discharging into Algoa Bay, South Africa. The results indicated that industrial Swartkops and metropolitan Baakens Rivers both illustrate moderate plastic pollution (>3000 plastic particles/day), with the relatively natural Sundays River to showing minimal evidence of river macroplastic (<100 plastic particles/day). The types of plastic were noted using the RIMMEL app (premier African implementation), enabling proportional comparison of different plastic litter types to be completed. , Thesis (MSc) -- Faculty of Science, Oceanography Department,2021
- Full Text:
- Date Issued: 2021-12
Post-apartheid geographies of studentification at Nelson Mandela University, Port Elizabeth, South Africa
- Authors: Mzileni, Pedro Mihlali
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10948/53758 , vital:45759
- Description: This study takes the concept of studentification from its British conception to the post-apartheid African city, Port Elizabeth (Gqeberha), where the Nelson Mandela University is situated. Studentification refers to the mass arrival of students in university cities and towns and the economic, infrastructural, geographic and sociopolitical changes that the settlements of these students make overtime to such cities and towns. For the case of Nelson Mandela University in Port Elizabeth, this study identified four major areas that are engulfed by studentification and sought to understand how this phenomenon takes shape in them. The study extends the existing terms and languages used to comprehend studentification by introducing a viewpoint of how it emerges in an African post-apartheid city. This is a city that has deindustrialised and has also experienced a capital flight out of its city centre since the 1970s. These declining economic indicators over decades have left the city to decay and experience high rates of unemployment, poverty and housing displacements. But, the post-1994 massification of the South African higher education system introduced new micro-economies for the city mainly through the emergence of student accommodation as a thriving business opportunity in the city in light of increased university enrolments. However, the economic injection brought by student accommodation in this city that has been deindustrialising remains minimal in having the necessary power to turnaround the city’s fortunes and transform the urban space towards a developmental path. This socioeconomic problem is also compounded by the presence of a weak arm of the state (particularly local government) that is unable to play an active role in driving capital flows to deliver tangible urban development. As a result, the university emerges as one of the active public actors in the renewal efforts of the city even though this is not its primary mandate. Thus, the process of studentification in this case takes place in a context defined by a declining higher education political economy and a weak city planning regime. As a result, these factors leave studentification to be vulnerable to being impacted by old colonial-apartheid structures of the city and the economic shortfalls of post-apartheid urban South Africa that have produced a precarious urban space where the private property market and the illicit economy have a stronger hand in determining the power relations that emerge in the city space. Studentification in this African city is expressed in four major geographies: (1) the Summerstrand suburb that is nearest to the University’s main urban campuses, (2) the Central CBD that has experienced capital flight and currently has tall buildings that are former offices of apartheid commerce which have been converted to student accommodation, (3) the deindustrialised and abandoned manufacturing sites at the North End margins of the city which have also been converted to student accommodation, and (4) the Zwide township, an underprivileged black community that is close to the former black Missionvale campus of the University – this is the furthest student accommodation area in the city. The study examines these student communities that emerge out of these four identified areas of the urban space and it also underscores the genre of the political, social, and economic relations of each of these four geographies and their interconnectedness. The study found that the South African post-apartheid city is characterised by an urban model and a university campus design that is a structural outcome of colonisation, apartheid spatial planning, and racial capitalism that still has continuing legacies today. As a result, these four geographies of studentification in the city are historical, racial and economic outcomes of urban power relations that originate from colonialism. Key defining features of studentification in each of these four areas were identified and analysed to illustrate that the South African account of studentification resembles the city’s apartheid legacy and these untransformed urban structures get further compounded by the country’s underfunded higher education massification strategy, its declining economic indicators and a weak state that has ‘soft’ planning and governance systems that are unable to decisively impact the trajectory of socioeconomic development in this university city. These intersecting forces translate into precarious day-to-day student life experiences and structural complications for the governance of the University and the city. These socioeconomic misfortunes also handicap the potential of the city to renew through a studentification economy. Henri Lefebvre’s Production of Space Theory was utilised to frame the study. Methodologically, the study utilised qualitative narrative interviews and document interpretation. This is the first doctoral thesis written about the concept of studentification in South Africa. , Thesis (PhD) -- Faculty of Humanities, The Department of Sociology and Anthropology, 2021
- Full Text:
- Date Issued: 2021-12
- Authors: Mzileni, Pedro Mihlali
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10948/53758 , vital:45759
- Description: This study takes the concept of studentification from its British conception to the post-apartheid African city, Port Elizabeth (Gqeberha), where the Nelson Mandela University is situated. Studentification refers to the mass arrival of students in university cities and towns and the economic, infrastructural, geographic and sociopolitical changes that the settlements of these students make overtime to such cities and towns. For the case of Nelson Mandela University in Port Elizabeth, this study identified four major areas that are engulfed by studentification and sought to understand how this phenomenon takes shape in them. The study extends the existing terms and languages used to comprehend studentification by introducing a viewpoint of how it emerges in an African post-apartheid city. This is a city that has deindustrialised and has also experienced a capital flight out of its city centre since the 1970s. These declining economic indicators over decades have left the city to decay and experience high rates of unemployment, poverty and housing displacements. But, the post-1994 massification of the South African higher education system introduced new micro-economies for the city mainly through the emergence of student accommodation as a thriving business opportunity in the city in light of increased university enrolments. However, the economic injection brought by student accommodation in this city that has been deindustrialising remains minimal in having the necessary power to turnaround the city’s fortunes and transform the urban space towards a developmental path. This socioeconomic problem is also compounded by the presence of a weak arm of the state (particularly local government) that is unable to play an active role in driving capital flows to deliver tangible urban development. As a result, the university emerges as one of the active public actors in the renewal efforts of the city even though this is not its primary mandate. Thus, the process of studentification in this case takes place in a context defined by a declining higher education political economy and a weak city planning regime. As a result, these factors leave studentification to be vulnerable to being impacted by old colonial-apartheid structures of the city and the economic shortfalls of post-apartheid urban South Africa that have produced a precarious urban space where the private property market and the illicit economy have a stronger hand in determining the power relations that emerge in the city space. Studentification in this African city is expressed in four major geographies: (1) the Summerstrand suburb that is nearest to the University’s main urban campuses, (2) the Central CBD that has experienced capital flight and currently has tall buildings that are former offices of apartheid commerce which have been converted to student accommodation, (3) the deindustrialised and abandoned manufacturing sites at the North End margins of the city which have also been converted to student accommodation, and (4) the Zwide township, an underprivileged black community that is close to the former black Missionvale campus of the University – this is the furthest student accommodation area in the city. The study examines these student communities that emerge out of these four identified areas of the urban space and it also underscores the genre of the political, social, and economic relations of each of these four geographies and their interconnectedness. The study found that the South African post-apartheid city is characterised by an urban model and a university campus design that is a structural outcome of colonisation, apartheid spatial planning, and racial capitalism that still has continuing legacies today. As a result, these four geographies of studentification in the city are historical, racial and economic outcomes of urban power relations that originate from colonialism. Key defining features of studentification in each of these four areas were identified and analysed to illustrate that the South African account of studentification resembles the city’s apartheid legacy and these untransformed urban structures get further compounded by the country’s underfunded higher education massification strategy, its declining economic indicators and a weak state that has ‘soft’ planning and governance systems that are unable to decisively impact the trajectory of socioeconomic development in this university city. These intersecting forces translate into precarious day-to-day student life experiences and structural complications for the governance of the University and the city. These socioeconomic misfortunes also handicap the potential of the city to renew through a studentification economy. Henri Lefebvre’s Production of Space Theory was utilised to frame the study. Methodologically, the study utilised qualitative narrative interviews and document interpretation. This is the first doctoral thesis written about the concept of studentification in South Africa. , Thesis (PhD) -- Faculty of Humanities, The Department of Sociology and Anthropology, 2021
- Full Text:
- Date Issued: 2021-12
Preventive diplomacy and conflict prevention in Africa: an examination of South Africa’s role in conflict resolution in the Democratic Republic of The Congo
- Authors: Mandela, Siyabulela
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10948/54471 , vital:46584
- Description: The Agenda 2063 tabled a blueprint of seven aspirations, for the Africa we want and one which was critical to this study being a peaceful and secure Africa. As postulated in this aspiration, by Agenda 2063, “Africa shall be free from armed conflict, terrorism, extremism, intolerance, and gender-based violence, which are major threats to human security, peace and development”. The Assembly of the AU committed in the agenda to fast-track actions to silence the guns by 2020, through enhanced dialogue-centred conflict prevention and resolution. The deadline for silencing guns and ending all wars in Africa was 2020, which has passed and Africa remains characterised by violent conflict and underdevelopment. Violent conflict of different magnitudes continues unabated across different states in Africa and remain insolent to any means towards resolution. The African continent is also a host to the most fragile states in the world, and the governments of these countries are unable to cultivate or facilitate the necessary conditions needed for sustainable peace and development. The conditions of poverty, frustration of basic human needs, maladministration, corruption, mismanagement of diversity and ethnic divisions so prevalent in Africa increase the likelihood of violent conflict. Conflict provention, preventive diplomacy, problem-solving workshops, peacebuilding and peacekeeping are all variants of peace operations deemed crucial in this study for Africa’s stability, peace and development. The advancement of preventive diplomacy and conflict provention as a hybrid framework for the prevention and resolution of violent conflict and promotion of sustainable peace and development in Africa was at the centre of this study. The study adopted John Burton’s basic human needs theory as a theoretical framework to further highlight an urgency by African states to prioritise policies and conflict resolution efforts directed at addressing the underlying issues giving rise to violent conflicts, if sustainable peace and development was to be realised in the continent. , Thesis (PhD) -- Faculty of Humanities, School of Governmental and Social Sciences, 2021
- Full Text:
- Date Issued: 2021-12
- Authors: Mandela, Siyabulela
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10948/54471 , vital:46584
- Description: The Agenda 2063 tabled a blueprint of seven aspirations, for the Africa we want and one which was critical to this study being a peaceful and secure Africa. As postulated in this aspiration, by Agenda 2063, “Africa shall be free from armed conflict, terrorism, extremism, intolerance, and gender-based violence, which are major threats to human security, peace and development”. The Assembly of the AU committed in the agenda to fast-track actions to silence the guns by 2020, through enhanced dialogue-centred conflict prevention and resolution. The deadline for silencing guns and ending all wars in Africa was 2020, which has passed and Africa remains characterised by violent conflict and underdevelopment. Violent conflict of different magnitudes continues unabated across different states in Africa and remain insolent to any means towards resolution. The African continent is also a host to the most fragile states in the world, and the governments of these countries are unable to cultivate or facilitate the necessary conditions needed for sustainable peace and development. The conditions of poverty, frustration of basic human needs, maladministration, corruption, mismanagement of diversity and ethnic divisions so prevalent in Africa increase the likelihood of violent conflict. Conflict provention, preventive diplomacy, problem-solving workshops, peacebuilding and peacekeeping are all variants of peace operations deemed crucial in this study for Africa’s stability, peace and development. The advancement of preventive diplomacy and conflict provention as a hybrid framework for the prevention and resolution of violent conflict and promotion of sustainable peace and development in Africa was at the centre of this study. The study adopted John Burton’s basic human needs theory as a theoretical framework to further highlight an urgency by African states to prioritise policies and conflict resolution efforts directed at addressing the underlying issues giving rise to violent conflicts, if sustainable peace and development was to be realised in the continent. , Thesis (PhD) -- Faculty of Humanities, School of Governmental and Social Sciences, 2021
- Full Text:
- Date Issued: 2021-12
Protean career management of independent music creatives in Gqeberha : narratives of practice
- Authors: Henneberry, Robyn
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/54439 , vital:46541
- Description: This study is concerned with the promotion of local music creatives. The literature explores ways to help the independent music creatives successfully navigate in the music industry by adopting a protean career profile. The research question that was explored in the study was whether or not the independent popular female creatives in the city of Gqeberha’s music industry adopted protean career profiles for successful career navigation. These pop music creatives’ profiles were compared to those of classical creatives for further insight. Relevant literature was analysed to collect data about what international authors have discovered about creatives’ successful navigation of their careers. The information that was gleaned from the analysis indicated that numerous individuals have adopted the profile of the protean career to successfully navigate their environment. The rationale for adopting the protean career profile was that it is directly related to one’s employability. Although the working world (including the music industry) is rapidly changing, this notion of employability will enable an individual to remain updated about the latest trends in their work environment and thus successfully navigate that environment. This concept was applied to research among music creatives in the South African (SA) context. Although there was limited research on the protean career profile, the published research findings that were available indicated that employability and information were in alliance with the international research on the protean career (which constitutes one’s employability). Employing qualitative data collection procedures, the researcher interviewed 14 independent female music creatives with different backgrounds, roles and experiences. Interviews were semi-structured one-on-one as well as focus groups. This narrative strategy of inquiry helped determine whether or not these individuals had adopted the protean career for successful navigation of their working environment. After data collection the researcher engaged in a cyclical coding process for deep analysation of the data utilising atlas.ti. The data was reduced from codes to categories, and eventually towards linking categories. The findings from the study revealed that the participants’ environment (surroundings) did not sufficiently support them, the creatives do not have sufficient guidance in their music paths and not all of them had adopted the protean profile. , Thesis (MA) -- Faculty of Humanities, School of Visual and Performing Arts, 2021
- Full Text:
- Date Issued: 2021-12
- Authors: Henneberry, Robyn
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/54439 , vital:46541
- Description: This study is concerned with the promotion of local music creatives. The literature explores ways to help the independent music creatives successfully navigate in the music industry by adopting a protean career profile. The research question that was explored in the study was whether or not the independent popular female creatives in the city of Gqeberha’s music industry adopted protean career profiles for successful career navigation. These pop music creatives’ profiles were compared to those of classical creatives for further insight. Relevant literature was analysed to collect data about what international authors have discovered about creatives’ successful navigation of their careers. The information that was gleaned from the analysis indicated that numerous individuals have adopted the profile of the protean career to successfully navigate their environment. The rationale for adopting the protean career profile was that it is directly related to one’s employability. Although the working world (including the music industry) is rapidly changing, this notion of employability will enable an individual to remain updated about the latest trends in their work environment and thus successfully navigate that environment. This concept was applied to research among music creatives in the South African (SA) context. Although there was limited research on the protean career profile, the published research findings that were available indicated that employability and information were in alliance with the international research on the protean career (which constitutes one’s employability). Employing qualitative data collection procedures, the researcher interviewed 14 independent female music creatives with different backgrounds, roles and experiences. Interviews were semi-structured one-on-one as well as focus groups. This narrative strategy of inquiry helped determine whether or not these individuals had adopted the protean career for successful navigation of their working environment. After data collection the researcher engaged in a cyclical coding process for deep analysation of the data utilising atlas.ti. The data was reduced from codes to categories, and eventually towards linking categories. The findings from the study revealed that the participants’ environment (surroundings) did not sufficiently support them, the creatives do not have sufficient guidance in their music paths and not all of them had adopted the protean profile. , Thesis (MA) -- Faculty of Humanities, School of Visual and Performing Arts, 2021
- Full Text:
- Date Issued: 2021-12
Quantifying variability of emissions of greenhouse gas (CO2& CH4) across selected soils and agricultural practices
- Authors: Sebake, Tebogo Matsimela
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/54107 , vital:46302
- Description: Increasing concentrations of greenhouse gases (GHG’s)in the atmosphere are warming the planet, and agriculture is responsible for about 30% of these emissions. Soils act as a host for greenhouse gases, since both their storage and emission capacities are large, accounting for two-times the amount of carbon in the atmosphere and in plant and animal life. It sequesters large amounts of carbon, and because agricultural practices depend on soil for production, the practices influence the soil’s ability to store the carbon effectively. Production soils emit greenhouse gas, predominantly carbon dioxide and methane, which are assessed for emissions in this study. Climate change creates unpredictability in precipitation and temperature; farmers need to be flexible and adapt production methods to such environmental changes in order to continue producing sustainably. Global food production needs to grow drastically to meet the projected demands for rising population and diet shifts; studies have shown that feeding a more populated and a more affluent, equal, world will require roughly a doubling of agricultural production by 2050, which means more GHG emissions from the soil. To enable better control on these emissions, their links to agricultural practices need to be better quantified. The study was done in two areas: (1) long-term comparative farming systems research trial with controlled vegetable plots, in the agricultural school of Nelson Mandela University, in George, Western Cape province and (2) long-term wheat research trial of the Free State University, in Bethlehem, Free State province. The objective in study area one is to assess and compare GHG emissions from conventional and organic systems. Temperature and soil moisture were measured during gas samples to establish the influence they have on gas emissions. The objective in study area two is to assess and compare GHG emissions from no-till, plough, and stubble mulch. Stubble mulch refers to crop residue left in place on the land as a surface cover during fallow periods. Two polypropylene canisters are placed in a sampled plot to trap gas emitted from the soil. Analyses of the trapped gases in the headspace gives concentrations of CO2and CH4that was emitted during the duration the canister was closed. The gas is analysed by a G2201-i Picarro gas analyser, presently the only such instrument in South Africa. The analyser’s near-infrared Cavity Ring Down Spectroscopy technology is capable of simultaneous measurements of CO2and CH4down to parts per million. In study area one, conventional plots (R2T6 & R1T6) emitted 65.089ppm CO2and 61.159ppm CO2, and 0.0010ppm CH4and 0.0004ppm CH4, respectively. Organic plots (R1T3 & R2T3) emitted 53.264ppm CO2and 47.885ppm CO2, and 0.0023ppm CH4and 0.0019ppm CH4respectively. Thus, conventional plots emitted 19.98% & 30.98% more CO2than organic plots; but organic plots emitted 81.97% & 155.5% more CH4thanconventional plots. In study area two, ploughed soils emitted 38.727ppm CO2and 0.015ppm CH4, no-tilled soils emitted 31.798ppm CO2 and 0.011ppm CH4andstubble mulched soils emitted 28.373ppm CO2 and 0.009ppm CH4. Thus, ploughed soils emitted 19.65%more CO2than no-tilled soils, no-tilled soils emitted 11.38% more CO2 than stubble mulched soils and ploughed soils emitted 30.36% more CO2 than stubble mulched soils. Ploughed soils emitted 30.77% more CH4 than no-tilled soils, no-tilled soils emitted 20% more CH4 than stubble mulched soils and ploughed soils emitted 50% more CH4than stubble mulched soils. Moist soils result in decreased CO2emissions in conventional plots and increased CH4emissions in organic plots. Increasing temperature patterns are followed by a trend of increasing gas emissions. Reducing GHG emissions from agriculture and developing sustainable tillage practices can help mitigate climate change and increases the chances of stabilizing GHG concentrations and temperature control within a required range. , Thesis (MSc) -- Faculty of Science, School of Environmental Sciences, 2021
- Full Text:
- Date Issued: 2021-12
- Authors: Sebake, Tebogo Matsimela
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/54107 , vital:46302
- Description: Increasing concentrations of greenhouse gases (GHG’s)in the atmosphere are warming the planet, and agriculture is responsible for about 30% of these emissions. Soils act as a host for greenhouse gases, since both their storage and emission capacities are large, accounting for two-times the amount of carbon in the atmosphere and in plant and animal life. It sequesters large amounts of carbon, and because agricultural practices depend on soil for production, the practices influence the soil’s ability to store the carbon effectively. Production soils emit greenhouse gas, predominantly carbon dioxide and methane, which are assessed for emissions in this study. Climate change creates unpredictability in precipitation and temperature; farmers need to be flexible and adapt production methods to such environmental changes in order to continue producing sustainably. Global food production needs to grow drastically to meet the projected demands for rising population and diet shifts; studies have shown that feeding a more populated and a more affluent, equal, world will require roughly a doubling of agricultural production by 2050, which means more GHG emissions from the soil. To enable better control on these emissions, their links to agricultural practices need to be better quantified. The study was done in two areas: (1) long-term comparative farming systems research trial with controlled vegetable plots, in the agricultural school of Nelson Mandela University, in George, Western Cape province and (2) long-term wheat research trial of the Free State University, in Bethlehem, Free State province. The objective in study area one is to assess and compare GHG emissions from conventional and organic systems. Temperature and soil moisture were measured during gas samples to establish the influence they have on gas emissions. The objective in study area two is to assess and compare GHG emissions from no-till, plough, and stubble mulch. Stubble mulch refers to crop residue left in place on the land as a surface cover during fallow periods. Two polypropylene canisters are placed in a sampled plot to trap gas emitted from the soil. Analyses of the trapped gases in the headspace gives concentrations of CO2and CH4that was emitted during the duration the canister was closed. The gas is analysed by a G2201-i Picarro gas analyser, presently the only such instrument in South Africa. The analyser’s near-infrared Cavity Ring Down Spectroscopy technology is capable of simultaneous measurements of CO2and CH4down to parts per million. In study area one, conventional plots (R2T6 & R1T6) emitted 65.089ppm CO2and 61.159ppm CO2, and 0.0010ppm CH4and 0.0004ppm CH4, respectively. Organic plots (R1T3 & R2T3) emitted 53.264ppm CO2and 47.885ppm CO2, and 0.0023ppm CH4and 0.0019ppm CH4respectively. Thus, conventional plots emitted 19.98% & 30.98% more CO2than organic plots; but organic plots emitted 81.97% & 155.5% more CH4thanconventional plots. In study area two, ploughed soils emitted 38.727ppm CO2and 0.015ppm CH4, no-tilled soils emitted 31.798ppm CO2 and 0.011ppm CH4andstubble mulched soils emitted 28.373ppm CO2 and 0.009ppm CH4. Thus, ploughed soils emitted 19.65%more CO2than no-tilled soils, no-tilled soils emitted 11.38% more CO2 than stubble mulched soils and ploughed soils emitted 30.36% more CO2 than stubble mulched soils. Ploughed soils emitted 30.77% more CH4 than no-tilled soils, no-tilled soils emitted 20% more CH4 than stubble mulched soils and ploughed soils emitted 50% more CH4than stubble mulched soils. Moist soils result in decreased CO2emissions in conventional plots and increased CH4emissions in organic plots. Increasing temperature patterns are followed by a trend of increasing gas emissions. Reducing GHG emissions from agriculture and developing sustainable tillage practices can help mitigate climate change and increases the chances of stabilizing GHG concentrations and temperature control within a required range. , Thesis (MSc) -- Faculty of Science, School of Environmental Sciences, 2021
- Full Text:
- Date Issued: 2021-12
Re-imagining Afrikaner masculinity through conceptual fashion design
- Authors: Smit, Dalton
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/54563 , vital:46708
- Description: Traditional Afrikaner culture has often been associated with conservative beliefs, giving patriarchal figures such as the husband and father superior status. Although South Africa has undergone social progression, large numbers in Afrikaner communities still live according to old, patriarchal norms. My perceptions of Afrikaner masculinity, informed by my cultural background, enforce patriarchy's functioning in some Afrikaner homes, allowing the development of rigid expectations of a male's self-expression. These mind-sets of what masculinity is do not align with my values, beliefs, and the visual presentation of my identity. With the application of autoethnographic inquiry in this practice-based study, I was able to analyse and interpret the nuanced discrimination against the performance of my male identity in an Afrikaner cultural context. I implemented autoethnographic and practice-based methods to respond to and challenge outdated and conservative views regarding the prevalence of Afrikaner masculine ideals and their negative implications. The contribution of the research practice is FYN BOI, a fictive persona constructed and performed by me. He represents a liberated facet of my identity whose reaction is rejection against the Afrikaner cultural opinions of me, and in turn, is fuelled by the criticism to provoke further and challenge these views. The conceptual garments created are considered his wardrobe, which he uses in his self-expression online. With this unconventional approach to a fashion study, disseminating the research practice online instead of a physical exhibition allows for the study to be accessed to audiences beyond academia's domain. This undertaking intends to contribute to the existing discourse of masculinity and prejudice against individuals' self-expression of their identity. , Thesis (MA) -- Faculty of Humanities, School of Visual and Performing Arts, 2021
- Full Text:
- Date Issued: 2021-12
- Authors: Smit, Dalton
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/54563 , vital:46708
- Description: Traditional Afrikaner culture has often been associated with conservative beliefs, giving patriarchal figures such as the husband and father superior status. Although South Africa has undergone social progression, large numbers in Afrikaner communities still live according to old, patriarchal norms. My perceptions of Afrikaner masculinity, informed by my cultural background, enforce patriarchy's functioning in some Afrikaner homes, allowing the development of rigid expectations of a male's self-expression. These mind-sets of what masculinity is do not align with my values, beliefs, and the visual presentation of my identity. With the application of autoethnographic inquiry in this practice-based study, I was able to analyse and interpret the nuanced discrimination against the performance of my male identity in an Afrikaner cultural context. I implemented autoethnographic and practice-based methods to respond to and challenge outdated and conservative views regarding the prevalence of Afrikaner masculine ideals and their negative implications. The contribution of the research practice is FYN BOI, a fictive persona constructed and performed by me. He represents a liberated facet of my identity whose reaction is rejection against the Afrikaner cultural opinions of me, and in turn, is fuelled by the criticism to provoke further and challenge these views. The conceptual garments created are considered his wardrobe, which he uses in his self-expression online. With this unconventional approach to a fashion study, disseminating the research practice online instead of a physical exhibition allows for the study to be accessed to audiences beyond academia's domain. This undertaking intends to contribute to the existing discourse of masculinity and prejudice against individuals' self-expression of their identity. , Thesis (MA) -- Faculty of Humanities, School of Visual and Performing Arts, 2021
- Full Text:
- Date Issued: 2021-12
Real-time feedback model for supporting individualised learning of programming students
- Authors: Keen, Charne
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/53624 , vital:45691
- Description: Feedback is crucial to the enhancement of the learning and teaching environment, especially in those environments that suffer from a number of extrinsic challenges. The growing demands for educators to provide academic interventions throughout the lecture session and the need for continuous improvement of the quality of university education make it necessary to find and apply more effective and efficient educational technologies and practices based on the correlation of teaching with a student’s conceptual understanding and individual learning preference. Following a combination of Design Science Research (DSR) and Case Study Methodology, this research addresses this problem by designing a technology based real-time feedback (TBRTF) model that can easily be implemented in a South African University. The model designed followed a layered architecture pattern. The architecture describes the data, technology and user support layers of the model. The data support layer incorporates the collection of student academic data and learning preferences. The technology incorporates a machine learning component. The machine learning component covers two technological aspects: the prediction component and the clustering component. This TBRTF model provides the guidelines needed to develop a system that supports individualised real-time feedback in the learning and teaching environment of programming students. The aim of the model is that as the students partake in learning activities where the student data is updated, the monitoring component will fire, updating the probability of failure prediction and in turn the student clusters are regenerated. This will notify the educator of a change and provide decision making support. The student will be allocated individualised feedback in the form of learning materials based on the cluster that the student is allocated to. Through a demonstration and evaluation, this study showed that by following the proposed architecture of the TBRTF model, a model that supports individualised realtime feedback in the learning and teaching environment of programming students can be developed. The validation used an artificial neural network as the prediction component and a k-means clustering algorithm as the clustering component. , Thesis (MSc) -- Faculty of Science, School of Computer Science, Mathematics, Physics and Statistics, 2021
- Full Text: false
- Date Issued: 2021-12
- Authors: Keen, Charne
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/53624 , vital:45691
- Description: Feedback is crucial to the enhancement of the learning and teaching environment, especially in those environments that suffer from a number of extrinsic challenges. The growing demands for educators to provide academic interventions throughout the lecture session and the need for continuous improvement of the quality of university education make it necessary to find and apply more effective and efficient educational technologies and practices based on the correlation of teaching with a student’s conceptual understanding and individual learning preference. Following a combination of Design Science Research (DSR) and Case Study Methodology, this research addresses this problem by designing a technology based real-time feedback (TBRTF) model that can easily be implemented in a South African University. The model designed followed a layered architecture pattern. The architecture describes the data, technology and user support layers of the model. The data support layer incorporates the collection of student academic data and learning preferences. The technology incorporates a machine learning component. The machine learning component covers two technological aspects: the prediction component and the clustering component. This TBRTF model provides the guidelines needed to develop a system that supports individualised real-time feedback in the learning and teaching environment of programming students. The aim of the model is that as the students partake in learning activities where the student data is updated, the monitoring component will fire, updating the probability of failure prediction and in turn the student clusters are regenerated. This will notify the educator of a change and provide decision making support. The student will be allocated individualised feedback in the form of learning materials based on the cluster that the student is allocated to. Through a demonstration and evaluation, this study showed that by following the proposed architecture of the TBRTF model, a model that supports individualised realtime feedback in the learning and teaching environment of programming students can be developed. The validation used an artificial neural network as the prediction component and a k-means clustering algorithm as the clustering component. , Thesis (MSc) -- Faculty of Science, School of Computer Science, Mathematics, Physics and Statistics, 2021
- Full Text: false
- Date Issued: 2021-12
Studies on seed germination and response to fertilization of Amaranthus accessions collected in the Eastern Cape Province, South Africa
- Ramangoele, Mpaballeng Alinah
- Authors: Ramangoele, Mpaballeng Alinah
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/54112 , vital:46307
- Description: Studies were conducted at Döhne Agricultural Development Institute (D.A.D.I.), geographically located between latitude 32°31'34.077"S and longitude 27°27'37.473"E in Stutterheim, Eastern Cape Province from summer 2018 until autumn 2019.The objectives were to determine seed germination and seedling vigour of four local Amaranthus accessions and to evaluate the effect of organic and inorganic fertilization on the growth, yield and nutrient composition. In the germination studies, herein referred to as Experiment 1,laboratory assessments were laid out in a Complete Randomized Design (CRD) replicated four times to test seed germination, seedling emergence and seedling vigour of four Amaranthus accessions namely: A. Hypochondriacus, A. Retroflexus 1, A. Hybridus and A. Retroflexus 2. Data collection included germination percentage, radicle length, co-efficient of velocity of germination and seedling vigour. A.Retroflexus2 gave the highest germination percentage in summer (85%) and autumn (87.75%).Seed weight resulted in the highest germination percentage and was observed to have shown a high positive correlation of {R2=0.91} in summer and{R2=0.92} in autumn respectively. The highest seedling vigour (p<0.001) in summer was attained from A. Hypochondriacus and A. Retroflexus2.In the greenhouse in summer, the highest emergence percentage was observed from A. Hypochondriacus(93.00%), whilst in autumn it was A.Retroflexus2 (88.38%).A. Retroflexus1 was the least performer in both seasons. In summer, A. Hypochondriacus and A. Retroflexus2 resulted in very high seedling vigour. In autumn A. Hypochondriacus, A. Retroflexus2 and A. Hybridus resulted in high seedling vigour and A. Retroflexus1 in moderate seedling vigour. The relationship observed between seed weight and seedling vigour showed a negative (inverse)correlation in summer {R2=0.58} and autumn {R2=0.62}.In Experiment 2, seedlings of A. Hypochondriacus and A. Retroflexus 2were transplanted in 5litrebasal perforated plastic pots which were filled with soil. The experimental layout was a CRD replicated four times. The treatments were: control (no amendment), goat manure, cattle manure and NPK fertilizer. Growth performance data were collected for plant height, the number of leaves and stem girth. In summer, when goat manure was applied both accessions resulted in the tallest plants (78.80cm) yet A. Retroflexus 2 and vA. Hypochondriacus gave the greatest stem girthand highest number of leaves respectively. In autumn, the tallest plants and highest number of leaves were observed from A. Retroflexus 2fertilized with NPK and the greatest stem girth was observed from A. Hypochondriacus fertilized with goat manure. The interaction of fertilization and accessions resulted in A. Retroflexus 2 fertilized with goat manure generating the greatest fresh shoot biomass (137.27g plant-1) and the least from the control. Both accessions fertilized with goat manure attained the greatest dry leaf biomass. Insummer, A.Retroflexus2 outperformed A. Hypochondriacus in calcium content despite the treatments. Unfertilized A. Retroflexus2 produced leaves with high potassium. Both unfertilized accessions showed the highest magnesium content. All A. Retroflexus2 treatments outperformed A. Hypochondriacus treatments on iron content except the control. The summer season was the best in terms of growth and yield of the tested accessions. , Thesis (MSc) -- Faculty of Science, School of Natural Resource Management, 2021
- Full Text:
- Date Issued: 2021-12
- Authors: Ramangoele, Mpaballeng Alinah
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/54112 , vital:46307
- Description: Studies were conducted at Döhne Agricultural Development Institute (D.A.D.I.), geographically located between latitude 32°31'34.077"S and longitude 27°27'37.473"E in Stutterheim, Eastern Cape Province from summer 2018 until autumn 2019.The objectives were to determine seed germination and seedling vigour of four local Amaranthus accessions and to evaluate the effect of organic and inorganic fertilization on the growth, yield and nutrient composition. In the germination studies, herein referred to as Experiment 1,laboratory assessments were laid out in a Complete Randomized Design (CRD) replicated four times to test seed germination, seedling emergence and seedling vigour of four Amaranthus accessions namely: A. Hypochondriacus, A. Retroflexus 1, A. Hybridus and A. Retroflexus 2. Data collection included germination percentage, radicle length, co-efficient of velocity of germination and seedling vigour. A.Retroflexus2 gave the highest germination percentage in summer (85%) and autumn (87.75%).Seed weight resulted in the highest germination percentage and was observed to have shown a high positive correlation of {R2=0.91} in summer and{R2=0.92} in autumn respectively. The highest seedling vigour (p<0.001) in summer was attained from A. Hypochondriacus and A. Retroflexus2.In the greenhouse in summer, the highest emergence percentage was observed from A. Hypochondriacus(93.00%), whilst in autumn it was A.Retroflexus2 (88.38%).A. Retroflexus1 was the least performer in both seasons. In summer, A. Hypochondriacus and A. Retroflexus2 resulted in very high seedling vigour. In autumn A. Hypochondriacus, A. Retroflexus2 and A. Hybridus resulted in high seedling vigour and A. Retroflexus1 in moderate seedling vigour. The relationship observed between seed weight and seedling vigour showed a negative (inverse)correlation in summer {R2=0.58} and autumn {R2=0.62}.In Experiment 2, seedlings of A. Hypochondriacus and A. Retroflexus 2were transplanted in 5litrebasal perforated plastic pots which were filled with soil. The experimental layout was a CRD replicated four times. The treatments were: control (no amendment), goat manure, cattle manure and NPK fertilizer. Growth performance data were collected for plant height, the number of leaves and stem girth. In summer, when goat manure was applied both accessions resulted in the tallest plants (78.80cm) yet A. Retroflexus 2 and vA. Hypochondriacus gave the greatest stem girthand highest number of leaves respectively. In autumn, the tallest plants and highest number of leaves were observed from A. Retroflexus 2fertilized with NPK and the greatest stem girth was observed from A. Hypochondriacus fertilized with goat manure. The interaction of fertilization and accessions resulted in A. Retroflexus 2 fertilized with goat manure generating the greatest fresh shoot biomass (137.27g plant-1) and the least from the control. Both accessions fertilized with goat manure attained the greatest dry leaf biomass. Insummer, A.Retroflexus2 outperformed A. Hypochondriacus in calcium content despite the treatments. Unfertilized A. Retroflexus2 produced leaves with high potassium. Both unfertilized accessions showed the highest magnesium content. All A. Retroflexus2 treatments outperformed A. Hypochondriacus treatments on iron content except the control. The summer season was the best in terms of growth and yield of the tested accessions. , Thesis (MSc) -- Faculty of Science, School of Natural Resource Management, 2021
- Full Text:
- Date Issued: 2021-12
Synthesis and characterization of iron doped sodium and potassium titanates using the pechini sol-gel method
- Authors: Guga, Aluwani
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/53646 , vital:45683
- Description: Iron doped (Fe: 5Ti) sodium and potassium titanates were prepared by the Pechini sol-gel method and calcined at 800 °C. X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive X-ray spectrometry (EDS), FTIR and Raman spectroscopy were used to characterize the structure and morphology of the titanate nanomaterials. A quantitative XRD analysis using Rietveld refinement of the titanates confirmed the powders to consist of crystalline phases with the Na2Ti7O15 and K2Ti8O17 phases predominant for the sodium and potassium titanate, respectively. This was further confirmed using selected area electron diffraction (SAED) in the TEM. SEM and TEM analyses indicated that the titanates are consistent with a nanostructured material exhibiting rod-like morphology. The elemental compositions of the titanites were examined by SEM-EDS and TEM-EDS and found to agree well with the targeted Fe to Ti ratio from synthesis. Limited evidence for the segregation of iron in the titanate regions were found indicating the iron to be incorporated within the titanate lattice. Electron energy loss spectroscopy (EELS) fine-structure analysis of the Fe L2,3 core-loss edge was successfully used to match the Fe to a 2+ or 3+ valence state, consistent with its occupation at Ti lattice sites. Finally, Fourier transform infrared spectroscopy (FTIR) and Raman spectroscopy were used to study the vibrational modes of the functional group of the sodium and potassium titanates. Vibrational modes consistent with previously reported findings for the titanate phases identified were found with no evidence of isolated Fe related modes. , Thesis (MSc) -- Faculty of Science, Computer Science, Mathematics, Physics and Statistics, 2021
- Full Text: false
- Date Issued: 2021-12
- Authors: Guga, Aluwani
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/53646 , vital:45683
- Description: Iron doped (Fe: 5Ti) sodium and potassium titanates were prepared by the Pechini sol-gel method and calcined at 800 °C. X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive X-ray spectrometry (EDS), FTIR and Raman spectroscopy were used to characterize the structure and morphology of the titanate nanomaterials. A quantitative XRD analysis using Rietveld refinement of the titanates confirmed the powders to consist of crystalline phases with the Na2Ti7O15 and K2Ti8O17 phases predominant for the sodium and potassium titanate, respectively. This was further confirmed using selected area electron diffraction (SAED) in the TEM. SEM and TEM analyses indicated that the titanates are consistent with a nanostructured material exhibiting rod-like morphology. The elemental compositions of the titanites were examined by SEM-EDS and TEM-EDS and found to agree well with the targeted Fe to Ti ratio from synthesis. Limited evidence for the segregation of iron in the titanate regions were found indicating the iron to be incorporated within the titanate lattice. Electron energy loss spectroscopy (EELS) fine-structure analysis of the Fe L2,3 core-loss edge was successfully used to match the Fe to a 2+ or 3+ valence state, consistent with its occupation at Ti lattice sites. Finally, Fourier transform infrared spectroscopy (FTIR) and Raman spectroscopy were used to study the vibrational modes of the functional group of the sodium and potassium titanates. Vibrational modes consistent with previously reported findings for the titanate phases identified were found with no evidence of isolated Fe related modes. , Thesis (MSc) -- Faculty of Science, Computer Science, Mathematics, Physics and Statistics, 2021
- Full Text: false
- Date Issued: 2021-12
The aesthetics of hegemony: a speculative design proposal exploring the convergence of surveillance capitalism and brain-computer interface technologies in the future
- Authors: Davies, James Tibbott
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/54417 , vital:46517
- Description: This study examines the power dynamics of surveillance capitalism, and its role in shaping cultural hegemony. The research was expressed using graphic design to illustrate a (potential) future where Brain-Computer Interfaces (BCIs) and surveillance capitalism converge. The critique focused on Google and Facebook’s hegemony in the data-surveillance marketplace and what role this has in shaping global discourse. Both companies are funding the development of BCIs, with the aim of using brain signals as a means of interacting with the digital world, which would give the two biggest advertising companies in the world access to new sources of data. A speculative design framework was utilized to visually question the societal implications of this emerging technology and the funding behind its development. A theoretical investigation of the concepts underpinning critical theory and critical design was conducted to help clarify and critically inform this methodological approach, promoting the use of practice-based design as a critically reflective investigative tool. The resulting artefacts designed using this process were showcased in the form of a website and video that act as a visual embodiment the research, demonstrating the efficacy of this approach and the value of using communication design as a mechanism to question the status quo. , Thesis (MA) -- Faculty of Humanities, School of Visual and Performing Arts, 2021
- Full Text:
- Date Issued: 2021-12
- Authors: Davies, James Tibbott
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/54417 , vital:46517
- Description: This study examines the power dynamics of surveillance capitalism, and its role in shaping cultural hegemony. The research was expressed using graphic design to illustrate a (potential) future where Brain-Computer Interfaces (BCIs) and surveillance capitalism converge. The critique focused on Google and Facebook’s hegemony in the data-surveillance marketplace and what role this has in shaping global discourse. Both companies are funding the development of BCIs, with the aim of using brain signals as a means of interacting with the digital world, which would give the two biggest advertising companies in the world access to new sources of data. A speculative design framework was utilized to visually question the societal implications of this emerging technology and the funding behind its development. A theoretical investigation of the concepts underpinning critical theory and critical design was conducted to help clarify and critically inform this methodological approach, promoting the use of practice-based design as a critically reflective investigative tool. The resulting artefacts designed using this process were showcased in the form of a website and video that act as a visual embodiment the research, demonstrating the efficacy of this approach and the value of using communication design as a mechanism to question the status quo. , Thesis (MA) -- Faculty of Humanities, School of Visual and Performing Arts, 2021
- Full Text:
- Date Issued: 2021-12
The benefits of community music on individuals in Port Elizabeth
- Authors: Rossouw, Carolyn
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/54552 , vital:46703
- Description: Countless research studies have outlined the benefits of Community Music engagement. Community Music is a global phenomenon that offers benefits to and across both international and national music projects. There are many forms of Community Music, including choral groups, instrumentalists, bands, and other ensembles. A variety of reasons or perspectives exist as to why participants engage in Community Music activities, such as the benefits that they gain when engaging in a project and/or the experiences of learning music in a social context. Characteristics of Community Music entail voluntary participation for individuals from all walks of life (e.g., those of high or low socio-economic standing, different races, and/or different levels of mental and/or emotional well-being). This study investigated three Community Music projects that take place at three different churches in Port Elizabeth, South Africa. The Community Music projects described in this study were different to those that are usually described in academic studies in so far as they are not aimed at social reform, social intervention, creative possibilities, or self-expression. Instead, this study focussed on investigating Community Music in Port Elizabeth based purely on creative possibilities and self-expression in order to better understand the benefits it can have on the individuals and community taking part therein. The Community Music projects described in this study involve both adult and youth participants and all fall under ‘church music’. Specifically, the projects consist of an adult church choir, a youth worship band, and an instrumental ensemble. In this qualitative study, a multiple case study approach was adopted, and data were gathered through observations, unstructured interviews, and both audio-visual and written materials. Themes emerged from the study that have been categorised as follows: social benefits, well-being benefits, spiritual benefits, musical skills development benefits, and leadership benefits. , Thesis (MA) -- Faculty of Humanities, School of Visual and Performing Arts, 2021
- Full Text:
- Date Issued: 2021-12
- Authors: Rossouw, Carolyn
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/54552 , vital:46703
- Description: Countless research studies have outlined the benefits of Community Music engagement. Community Music is a global phenomenon that offers benefits to and across both international and national music projects. There are many forms of Community Music, including choral groups, instrumentalists, bands, and other ensembles. A variety of reasons or perspectives exist as to why participants engage in Community Music activities, such as the benefits that they gain when engaging in a project and/or the experiences of learning music in a social context. Characteristics of Community Music entail voluntary participation for individuals from all walks of life (e.g., those of high or low socio-economic standing, different races, and/or different levels of mental and/or emotional well-being). This study investigated three Community Music projects that take place at three different churches in Port Elizabeth, South Africa. The Community Music projects described in this study were different to those that are usually described in academic studies in so far as they are not aimed at social reform, social intervention, creative possibilities, or self-expression. Instead, this study focussed on investigating Community Music in Port Elizabeth based purely on creative possibilities and self-expression in order to better understand the benefits it can have on the individuals and community taking part therein. The Community Music projects described in this study involve both adult and youth participants and all fall under ‘church music’. Specifically, the projects consist of an adult church choir, a youth worship band, and an instrumental ensemble. In this qualitative study, a multiple case study approach was adopted, and data were gathered through observations, unstructured interviews, and both audio-visual and written materials. Themes emerged from the study that have been categorised as follows: social benefits, well-being benefits, spiritual benefits, musical skills development benefits, and leadership benefits. , Thesis (MA) -- Faculty of Humanities, School of Visual and Performing Arts, 2021
- Full Text:
- Date Issued: 2021-12
The effect of silicon on palladium migration in pyrolytic carbon and graphite
- Authors: Downey, Justin Michael
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10948/53665 , vital:45684
- Description: The pebble-bed reactor (PBR) is a graphite-moderated, gas-cooled high temperature nuclear reactor design and it is one of six nuclear reactor concepts included in the Generation IV initiative. Pebble-bed reactors use spherical fuel elements (called pebbles) which consist of pyrolytic graphite (which acts as the moderator) and contain thousands of micro-fuel particles called tristructural isotropic (TRISO) particles. These TRISO fuel particles consist of a fissile material (such as U235 in oxide or carbide form) surrounded by a carbon buffer layer, a pyrolytic carbon (PyC) layer, a silicon carbide (SiC) ceramic layer for structural integrity and metallic fission product containment, and an outer PyC layer. The PBR is claimed to be a passively safe design. The commercial development of the first pebble bed reactor was that of the German AVR reactor (German: Arbeitsgemeinschaft Versuchsreaktor) developed during the 1960s. The AVR design was later updated and marketed by a company called HTR. In 1999 the South African electricity company ESKOM obtained the right to access the HTR engineering database that included details of the Siemens/Interatom HTR-Module design. ESKOM worked with HTR on a new design and dubbed it the pebble bed modular reactor (PBMR). The PBMR Co. Ltd. was formed in 1999 and mandated to license and build PBMR reactors. One of the safety considerations which emerged from research is that of metal fission product release from the TRISO fuel particles. Ag110m is a radioactive metallic fission product found to have been released from intact TRISO particles. The release of this Ag isotope is of particular concern because it is highly gamma active and has a half-life of approximately 250 days, resulting in unsafe environments for maintenance workers of PBRs. During the past four decades, many different mechanisms for Ag transport in SiC and release from TRISO particles have been proposed. A promising more recent mechanism suggests that the metallic fission product palladium (Pd) plays a significant role in the transport and release of Ag from intact TRISO particles. In this mechanism Ag transport in irradiated TRISO particle fuel takes place in the presence of the fission product Pd. The Pd reacts with the SiC layer and penetrates the SiC layer along grain boundaries to form a silicide layer which provides a rapid diffusion path for Ag in the SiC. The presence of thin silicide layers in irradiated TRISO particles was subsequently confirmed. , Thesis (PhD) -- Faculty of Science, School of Computer Science, Mathematics, Physics and Statistics, 2021
- Full Text: false
- Date Issued: 2021-12
- Authors: Downey, Justin Michael
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10948/53665 , vital:45684
- Description: The pebble-bed reactor (PBR) is a graphite-moderated, gas-cooled high temperature nuclear reactor design and it is one of six nuclear reactor concepts included in the Generation IV initiative. Pebble-bed reactors use spherical fuel elements (called pebbles) which consist of pyrolytic graphite (which acts as the moderator) and contain thousands of micro-fuel particles called tristructural isotropic (TRISO) particles. These TRISO fuel particles consist of a fissile material (such as U235 in oxide or carbide form) surrounded by a carbon buffer layer, a pyrolytic carbon (PyC) layer, a silicon carbide (SiC) ceramic layer for structural integrity and metallic fission product containment, and an outer PyC layer. The PBR is claimed to be a passively safe design. The commercial development of the first pebble bed reactor was that of the German AVR reactor (German: Arbeitsgemeinschaft Versuchsreaktor) developed during the 1960s. The AVR design was later updated and marketed by a company called HTR. In 1999 the South African electricity company ESKOM obtained the right to access the HTR engineering database that included details of the Siemens/Interatom HTR-Module design. ESKOM worked with HTR on a new design and dubbed it the pebble bed modular reactor (PBMR). The PBMR Co. Ltd. was formed in 1999 and mandated to license and build PBMR reactors. One of the safety considerations which emerged from research is that of metal fission product release from the TRISO fuel particles. Ag110m is a radioactive metallic fission product found to have been released from intact TRISO particles. The release of this Ag isotope is of particular concern because it is highly gamma active and has a half-life of approximately 250 days, resulting in unsafe environments for maintenance workers of PBRs. During the past four decades, many different mechanisms for Ag transport in SiC and release from TRISO particles have been proposed. A promising more recent mechanism suggests that the metallic fission product palladium (Pd) plays a significant role in the transport and release of Ag from intact TRISO particles. In this mechanism Ag transport in irradiated TRISO particle fuel takes place in the presence of the fission product Pd. The Pd reacts with the SiC layer and penetrates the SiC layer along grain boundaries to form a silicide layer which provides a rapid diffusion path for Ag in the SiC. The presence of thin silicide layers in irradiated TRISO particles was subsequently confirmed. , Thesis (PhD) -- Faculty of Science, School of Computer Science, Mathematics, Physics and Statistics, 2021
- Full Text: false
- Date Issued: 2021-12
The impact of institutional cultures on student’s wellbeing among postgraduate students: the case of Nelson Mandela University in South Africa
- Authors: Lebelo, Mpho Tiny
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/55402 , vital:51990
- Description: Increasingly, students across the world in various tertiary institutions are faced with many challenges ranging from financial difficulties, accommodation, academic exclusion and many other challenges. Subsequently, the students’ academic performance suffers due to these challenges. This thesis therefore aims to focus on the perspectives of the post-graduate students at the Nelson Mandela University regarding the notion of wellbeing. This thesis attempts to uses a sociological indigenous perspective of wellbeing of “impilo” in describing well-being. Therefore, the thesis uses wellness as a conceptual framework to understand the challenges faced by postgraduate students at Nelson Mandela University. The thesis was conducted in Port Elizabeth, at Nelson Mandela University campus of Summerstrand focusing on post-graduate students in faculty of humanities. A qualitative research design and qualitative digital ethnographic research methodology was chosen as suitable for answering the research question. Data was collected using semi-structured interviews and transcribed verbatim. Data analysis included identifying consistent themes around notions of well-being and experiences of changing university culture in the responses. The thesis main findings reveal the impact of how the changing university institutional culture impacts post-graduate student’s wellbeing.The research found that students are affected by institutional cultures and this is narrated through their experience of university life and their reflections on #MustFall movements. The participants have detailed how the cultures in the university have a greater impact on the well-being on student because the university is more than just a place of learning but their home. The participants also detailed new colloquial ways of describing well-being using the term “inerves” and “umgowo” are general ways of describing their well-being. The dissertation has contributed to the limited body of knowledge in the context of post-graduate students experience and conception of well-being in the South African higher education. , Thesis (MA) -- Faculty of Humanities, School of Governmental and Social Sciences, 2021
- Full Text:
- Date Issued: 2021-12
- Authors: Lebelo, Mpho Tiny
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/55402 , vital:51990
- Description: Increasingly, students across the world in various tertiary institutions are faced with many challenges ranging from financial difficulties, accommodation, academic exclusion and many other challenges. Subsequently, the students’ academic performance suffers due to these challenges. This thesis therefore aims to focus on the perspectives of the post-graduate students at the Nelson Mandela University regarding the notion of wellbeing. This thesis attempts to uses a sociological indigenous perspective of wellbeing of “impilo” in describing well-being. Therefore, the thesis uses wellness as a conceptual framework to understand the challenges faced by postgraduate students at Nelson Mandela University. The thesis was conducted in Port Elizabeth, at Nelson Mandela University campus of Summerstrand focusing on post-graduate students in faculty of humanities. A qualitative research design and qualitative digital ethnographic research methodology was chosen as suitable for answering the research question. Data was collected using semi-structured interviews and transcribed verbatim. Data analysis included identifying consistent themes around notions of well-being and experiences of changing university culture in the responses. The thesis main findings reveal the impact of how the changing university institutional culture impacts post-graduate student’s wellbeing.The research found that students are affected by institutional cultures and this is narrated through their experience of university life and their reflections on #MustFall movements. The participants have detailed how the cultures in the university have a greater impact on the well-being on student because the university is more than just a place of learning but their home. The participants also detailed new colloquial ways of describing well-being using the term “inerves” and “umgowo” are general ways of describing their well-being. The dissertation has contributed to the limited body of knowledge in the context of post-graduate students experience and conception of well-being in the South African higher education. , Thesis (MA) -- Faculty of Humanities, School of Governmental and Social Sciences, 2021
- Full Text:
- Date Issued: 2021-12
The impact of institutional cultures on student’s wellbeing among postgraduate students: the case of Nelson Mandela University in South Africa
- Authors: Lebelo, Mpho
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/54450 , vital:46549
- Description: Increasingly, students across the world in various tertiary institutions are faced with many challenges ranging from financial difficulties, accommodation, academic exclusion and many other challenges. Subsequently, the students’ academic performance suffers due to these challenges. This thesis therefore aims to focus on the perspectives of the post-graduate students at the Nelson Mandela University regarding the notion of wellbeing. This thesis attempts to uses a sociological indigenous perspective of wellbeing of “impilo” in describing well-being. Therefore, the thesis uses wellness as a conceptual framework to understand the challenges faced by postgraduate students at Nelson Mandela University. The thesis was conducted in Port Elizabeth, at Nelson Mandela University campus of Summerstrand focusing on post-graduate students in faculty of humanities. A qualitative research design and qualitative digital ethnographic research methodology was chosen as suitable for answering the research question. Data was collected using semi-structured interviews and transcribed verbatim. Data analysis included identifying consistent themes around notions of well-being and experiences of changing university culture in the responses. The thesis main findings reveal the impact of how the changing university institutional culture impacts post-graduate student’s wellbeing. The research found that students are affected by institutional cultures and this is narrated through their experience of university life and their reflections on #MustFall movements. The participants have detailed how the cultures in the university have a greater impact on the well-being on student because the university is more than just a place of learning but their home. The participants also detailed new colloquial ways of describing well-being using the term “inerves” and “umgowo” are general ways of describing their well-being. The dissertation has contributed to the limited body of knowledge in the context of post-graduate students experience and conception of well-being in the South African higher education. , Thesis (MA) -- Faculty of Humanities, School of Governmental and Social Sciences, 2021
- Full Text:
- Date Issued: 2021-12
- Authors: Lebelo, Mpho
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/54450 , vital:46549
- Description: Increasingly, students across the world in various tertiary institutions are faced with many challenges ranging from financial difficulties, accommodation, academic exclusion and many other challenges. Subsequently, the students’ academic performance suffers due to these challenges. This thesis therefore aims to focus on the perspectives of the post-graduate students at the Nelson Mandela University regarding the notion of wellbeing. This thesis attempts to uses a sociological indigenous perspective of wellbeing of “impilo” in describing well-being. Therefore, the thesis uses wellness as a conceptual framework to understand the challenges faced by postgraduate students at Nelson Mandela University. The thesis was conducted in Port Elizabeth, at Nelson Mandela University campus of Summerstrand focusing on post-graduate students in faculty of humanities. A qualitative research design and qualitative digital ethnographic research methodology was chosen as suitable for answering the research question. Data was collected using semi-structured interviews and transcribed verbatim. Data analysis included identifying consistent themes around notions of well-being and experiences of changing university culture in the responses. The thesis main findings reveal the impact of how the changing university institutional culture impacts post-graduate student’s wellbeing. The research found that students are affected by institutional cultures and this is narrated through their experience of university life and their reflections on #MustFall movements. The participants have detailed how the cultures in the university have a greater impact on the well-being on student because the university is more than just a place of learning but their home. The participants also detailed new colloquial ways of describing well-being using the term “inerves” and “umgowo” are general ways of describing their well-being. The dissertation has contributed to the limited body of knowledge in the context of post-graduate students experience and conception of well-being in the South African higher education. , Thesis (MA) -- Faculty of Humanities, School of Governmental and Social Sciences, 2021
- Full Text:
- Date Issued: 2021-12
The impact of transformed landscapes on the resource selection and occupancy of specialized browsing species in a lowland fynbos and renosterveld ecosystem
- Swanepoel, Hermanus Izak Johannes
- Authors: Swanepoel, Hermanus Izak Johannes
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/54132 , vital:46308
- Description: Human activities have dramatically transformed the natural environment over the last century. In most cases these activities have resulted in the destruction and fragmentation of habitats. However, in some areas the transformation of landscapes through agriculture have created novel habitats which could benefit some species. The effect of these transformed landscapes on the resource selection and occupancy of antelope species in different vegetation types such as fynbos and renosterveld are still understudied. In order to investigate this,we conducted a study in the Overberg region of the Western Cape, South Africa. We studied theoccupancy and habitat useof five specialist browsing species (Tragelaphus scriptus sylvaticus(bushbuck), Rhaphicerus melanotis(cape grysbok), Sylvicapra grimmia(common duiker), Palea Capreolus(grey rhebok) and Rhaphicerus campestris(steenbok)) within a transformed landscape. We collected speciesdetection/ non-detectionand presence/ absence data using camera traps and road strip counts.Usinga single season, single species occupancy framework as a surrogate for habitat usewedeterminedhow transformed landscapes affected their occupancy. Using aniche factor analysis and resource selection functions wedetermine how transformed landscapes affected the resource selectionof these species. Our results from the resource selection analysis indicated that steenbok, grey rhebok, andcommon duiker included crops such as wheat and planted pastures in their resource selection while also including natural vegetation. Cape grysbok and bushbuck selected predominantly for natural vegetation areas such as critical biodiversity areas and ecological support areas while also including some crops in their resource selection. Our results from the occupancy analysis indicatedthat steenbok, grey rhebok and common duiker had a higher occupancy in the transformed landscape than in the natural landscape. Bushbuck and Cape grysbok showed little to no difference in their occupancy between land use types. The insight provided by our results will allow practitioners to maximise the potentialof these mosaic landscape in the Overberg for mammal conservation.The study also provides a baseline from which further research and monitoring programs can be developed to further understand the dynamics of this landscape. , Thesis (MSc) -- Faculty of Science, School of Natural Resource Management, 2021
- Full Text:
- Date Issued: 2021-12
- Authors: Swanepoel, Hermanus Izak Johannes
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/54132 , vital:46308
- Description: Human activities have dramatically transformed the natural environment over the last century. In most cases these activities have resulted in the destruction and fragmentation of habitats. However, in some areas the transformation of landscapes through agriculture have created novel habitats which could benefit some species. The effect of these transformed landscapes on the resource selection and occupancy of antelope species in different vegetation types such as fynbos and renosterveld are still understudied. In order to investigate this,we conducted a study in the Overberg region of the Western Cape, South Africa. We studied theoccupancy and habitat useof five specialist browsing species (Tragelaphus scriptus sylvaticus(bushbuck), Rhaphicerus melanotis(cape grysbok), Sylvicapra grimmia(common duiker), Palea Capreolus(grey rhebok) and Rhaphicerus campestris(steenbok)) within a transformed landscape. We collected speciesdetection/ non-detectionand presence/ absence data using camera traps and road strip counts.Usinga single season, single species occupancy framework as a surrogate for habitat usewedeterminedhow transformed landscapes affected their occupancy. Using aniche factor analysis and resource selection functions wedetermine how transformed landscapes affected the resource selectionof these species. Our results from the resource selection analysis indicated that steenbok, grey rhebok, andcommon duiker included crops such as wheat and planted pastures in their resource selection while also including natural vegetation. Cape grysbok and bushbuck selected predominantly for natural vegetation areas such as critical biodiversity areas and ecological support areas while also including some crops in their resource selection. Our results from the occupancy analysis indicatedthat steenbok, grey rhebok and common duiker had a higher occupancy in the transformed landscape than in the natural landscape. Bushbuck and Cape grysbok showed little to no difference in their occupancy between land use types. The insight provided by our results will allow practitioners to maximise the potentialof these mosaic landscape in the Overberg for mammal conservation.The study also provides a baseline from which further research and monitoring programs can be developed to further understand the dynamics of this landscape. , Thesis (MSc) -- Faculty of Science, School of Natural Resource Management, 2021
- Full Text:
- Date Issued: 2021-12
The importance of public officials’ knowledge and understanding of the constitutional principles of public administration
- Authors: Zameko, Zamuxolo
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/54596 , vital:46732
- Description: Public officials in South Africa have been accused of lacking accountability, transparency, corruption, inefficiencies, unethical practices and a general unmotivated approach to service delivery. Section 195 of the 1996 constitution emphasises the need for public officials to be efficient, effective and not to be partial in their execution of duty. On that basis the research sought to investigate whether the public officials can improve on their performance if they are exposed to and are knowledgeable of the constitution. The study utilized a qualitative research method and a document analysis in which documents which served as sources of information were selected based on their relevance to the subject area of Public Administration. The documents selected were legal instruments used to enforce the operations of public officials including the Constitution of South Africa (1996), Batho Pele, White Paper on the Transformation of the Public Service, 1995; Promotion of Access to Information (Act no 2 of 2000 and Promotion of Equality & Prevention of Unfair Discrimination (Ac no 4 of 2000) Findings of the research indicate that key skills of the public officials like effective communication, change management, conflict resolution, decision-making, negotiation and accountability can be enhanced if they are knowledgeable of their constitutional mandate. The Public Service board should among others emphasize on constitutional principles training of all its employees upon recruitment such that they are aware of the public expectations. Continuous on the job training should also be offered to public officials so that their operations are always adjusted to the prevailing environmental and technological conditions. , Thesis (MA) -- Faculty of Humanities, School of Governmental and Social Sciences, 2021
- Full Text:
- Date Issued: 2021-12
- Authors: Zameko, Zamuxolo
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/54596 , vital:46732
- Description: Public officials in South Africa have been accused of lacking accountability, transparency, corruption, inefficiencies, unethical practices and a general unmotivated approach to service delivery. Section 195 of the 1996 constitution emphasises the need for public officials to be efficient, effective and not to be partial in their execution of duty. On that basis the research sought to investigate whether the public officials can improve on their performance if they are exposed to and are knowledgeable of the constitution. The study utilized a qualitative research method and a document analysis in which documents which served as sources of information were selected based on their relevance to the subject area of Public Administration. The documents selected were legal instruments used to enforce the operations of public officials including the Constitution of South Africa (1996), Batho Pele, White Paper on the Transformation of the Public Service, 1995; Promotion of Access to Information (Act no 2 of 2000 and Promotion of Equality & Prevention of Unfair Discrimination (Ac no 4 of 2000) Findings of the research indicate that key skills of the public officials like effective communication, change management, conflict resolution, decision-making, negotiation and accountability can be enhanced if they are knowledgeable of their constitutional mandate. The Public Service board should among others emphasize on constitutional principles training of all its employees upon recruitment such that they are aware of the public expectations. Continuous on the job training should also be offered to public officials so that their operations are always adjusted to the prevailing environmental and technological conditions. , Thesis (MA) -- Faculty of Humanities, School of Governmental and Social Sciences, 2021
- Full Text:
- Date Issued: 2021-12
The synthesis of anastrazole intermediates using continuous flow systems
- Authors: Tanyi, Sam Tambi
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/54116 , vital:46304
- Description: In this study, the continuous flow synthesis of anastrozole intermediates were investigated using mesitylene as starting material. Anastrozole is an important drug used for the treatment of breast cancer. In the first step, mesitylene was brominated using N-bromosuccinimide to obtain 3,5-bis(bromomethyl)toluene. Selectivity became an issue due to the formation of two by-products; namely 1,3,5-tris(bromomethyl) benzene (the tribrominated by-product) and 1-(bromomethyl)-3,5-dimethylbenzene (the monobrominated by-product). Since the reaction parameters can be more precisely controlled in flow chemistry systems, we were able to optimize the formation the desired product 3,5-bis(bromomethyl)toluene. The reaction was initially optimized ina 15μLChemtrix glass micro reactor resulting in 100%conversion with 95%selectivity towards the desired product 3,5-bis(bromomethyl)toluenein 15 seconds, with a throughput of 0.006 g/h. The reaction was then scaled up in a 1.7 mLLTF reactor, equally yielding 100%conversion with 95%selectivityin 4minutes, with a throughput of2.01g/h. The bromination of mesitylene was also attempted in a homemade photochemical reactor consisting of a 3.02 polytetrafluoroethylene coil reactor and BLE-6T365 UV lamp. In this photochemical reactor, although 100%conversionwas again obtained only75%selectivity was achieved in 20minutes, with a throughput of 0.025g/h. This drop in selectivity was attributed to poorer mixing in the larger polytetrafluoroethylene coil reactor and possibly insufficient light penetration. The next step, involving the cyanation of 3,5-bis(bromomethyl)toluene to obtain 2,2'-(5-methyl-1,3-phenylene) diacetonitrilegave 100%conversion in 1 minute at 190 °C in a 1.7 mLLTFreactor, with a throughput of 5.2g/h. The subsequent methylation of 3,5-bis(cyanomethyl)toluene to obtain3,5-bis(1-cyano-1-methylethyl) toluene was investigated using a1mLpolytetrafluoroethylenecoil reactor, ultimatelyachieving99%conversionat40 °Cin 8minutes, with a throughput of 0.045g/h. Next, the bromination of3,5-bis(1-cyano-1-methylethyl)toluene using N-bromosuccinimideto yield 2,2'-(5-bromomethyl-1,3-phenylene)di(2-methyl propionitrile) gave 100%conversion at 120 °C in 4 minutes, with a throughput of 0.35g/h. Lastly, the multistep synthesis of 3,5-bis(cyanomethyl)toluene was done in two integrated 1.7 mLLTF reactors, using the predetermined optimum conditions to achieve 94%conversion towards 3,5-bis(cyanomethyl)toluene with a total r , Thesis (MSc) -- Faculty of Science, School of Biomolecular and Chemical Sciences, 2021
- Full Text:
- Date Issued: 2021-12
- Authors: Tanyi, Sam Tambi
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/54116 , vital:46304
- Description: In this study, the continuous flow synthesis of anastrozole intermediates were investigated using mesitylene as starting material. Anastrozole is an important drug used for the treatment of breast cancer. In the first step, mesitylene was brominated using N-bromosuccinimide to obtain 3,5-bis(bromomethyl)toluene. Selectivity became an issue due to the formation of two by-products; namely 1,3,5-tris(bromomethyl) benzene (the tribrominated by-product) and 1-(bromomethyl)-3,5-dimethylbenzene (the monobrominated by-product). Since the reaction parameters can be more precisely controlled in flow chemistry systems, we were able to optimize the formation the desired product 3,5-bis(bromomethyl)toluene. The reaction was initially optimized ina 15μLChemtrix glass micro reactor resulting in 100%conversion with 95%selectivity towards the desired product 3,5-bis(bromomethyl)toluenein 15 seconds, with a throughput of 0.006 g/h. The reaction was then scaled up in a 1.7 mLLTF reactor, equally yielding 100%conversion with 95%selectivityin 4minutes, with a throughput of2.01g/h. The bromination of mesitylene was also attempted in a homemade photochemical reactor consisting of a 3.02 polytetrafluoroethylene coil reactor and BLE-6T365 UV lamp. In this photochemical reactor, although 100%conversionwas again obtained only75%selectivity was achieved in 20minutes, with a throughput of 0.025g/h. This drop in selectivity was attributed to poorer mixing in the larger polytetrafluoroethylene coil reactor and possibly insufficient light penetration. The next step, involving the cyanation of 3,5-bis(bromomethyl)toluene to obtain 2,2'-(5-methyl-1,3-phenylene) diacetonitrilegave 100%conversion in 1 minute at 190 °C in a 1.7 mLLTFreactor, with a throughput of 5.2g/h. The subsequent methylation of 3,5-bis(cyanomethyl)toluene to obtain3,5-bis(1-cyano-1-methylethyl) toluene was investigated using a1mLpolytetrafluoroethylenecoil reactor, ultimatelyachieving99%conversionat40 °Cin 8minutes, with a throughput of 0.045g/h. Next, the bromination of3,5-bis(1-cyano-1-methylethyl)toluene using N-bromosuccinimideto yield 2,2'-(5-bromomethyl-1,3-phenylene)di(2-methyl propionitrile) gave 100%conversion at 120 °C in 4 minutes, with a throughput of 0.35g/h. Lastly, the multistep synthesis of 3,5-bis(cyanomethyl)toluene was done in two integrated 1.7 mLLTF reactors, using the predetermined optimum conditions to achieve 94%conversion towards 3,5-bis(cyanomethyl)toluene with a total r , Thesis (MSc) -- Faculty of Science, School of Biomolecular and Chemical Sciences, 2021
- Full Text:
- Date Issued: 2021-12
The synthesis, empirical and theoretical studies of various (N→B) diarylborinate esters
- Authors: Manana, Pholani Sakhile
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10948/53869 , vital:46027
- Description: A series of core-functionalized borinic acids was synthesized from Grignard reagents and tributylborate and reacted with ethanolamine, amino acids, 2-pyridylmethanol as well as 2-(ethyl amino ethanol). Among the borinic acids synthesized were the ones bearing: para-(2, 15, 16, 22, 27)-methyl, (3, 20, 25)-chloro, (4, 23, 26)-fluoro, (5)-methoxy; meta-(7, 17)-methyl, (9)-fluoro; ortho-(6)-methyl, (8)-chloro, (10, 18, 19)-methoxy substituents on their respective aromatic systems. All compounds obtained by condensation of the borinic acids with the aforementioned nitrogen-containing substrates were characterized structurally by means of diffraction studies based on single crystals and found to constitute chelate esters/amides featuring covalent B-O and dative N→B bonds. The chelate compounds researched in this study could be classified into four families and represent the compounds: ethanol amine: (1) 2,2-diphenyl-1,3,2-oxazaborolidines, (2) 2,2-bis(p-tolyl)-1,3,2-oxazaborolidines, (3) 2,2-bis(p-chlorophenyl)-1,3,2-oxazaborolidines, (4) 2,2-bis(p-fluorophenyl)-1,3,2-oxazaborolidines, (5) 2,2-bis(p-methoxyphenyl)-1,3,2-oxazaborolidines, (6) 2,2-bis(o-tolyl)-1,3,2-oxazaborolidines, (7) 2,2-bis(m-tolyl)-1,3,2-oxazaborolidines, (8) 2,2-bis(o-chlorophenyl)-1,3,2-oxazaborolidines, (9) 2,2-bis(m-fluorophenyl)-1,3,2-oxazaborolidines, (10) 2,2-bis(o-methoxyphenyl)-1,3,2-oxazaborolidines. α-amino acids : (14) 4-methyl-2,2-diphenyl-1,3,2-oxazaborolidin-5-ones, (15) 2,2-bis(p-tolyl)-1,3,2-oxazaborolidin-5-ones, (16) 4-methyl-2,2-bis(p-tolyl)-1,3,2-oxazaborolidin-5-ones, (17) 4-isopropyl-2,2-bis(m-tolyl)-1,3,2-oxazaborolidin-5-ones, (18) 4-methyl-2,2-bis(o-methoxyphenyl)-1,3,2- oxazaborolidin-5-ones, (19) 4-acetamidyl-2,2-bis(o-methoxyphenyl)-1,3,2- oxazaborolidin-5-ones, (20) 4-phenylethane-2,2-bis(p-chlorophenyl)-1,3,2 oxazaborolidin-5-ones. 2-pyridylmethanol: (21) 1,3-hydroxypyridyl-2,2-diphenyl 1,3,2-oxazaborolidines, (22) 1,3-hydroxypyridyl-2,2-bis(p-tolyl)-1,3,2-oxazaborolidines, (23) 1,3-hydroxypyridyl-2,2-bis(p-fluorophenyl)-1,3,2-oxazaborolidines 2-(ethyl amino ethanol): (24) 3-ethyl-2,2-diphenyl-1,3,2-oxazaborolidines, (25) 3-ethyl-2,2-bis(p-chlorophenyl)-1,3,2-oxazaborolidines, (26) 3-ethyl-2,2-bis(p-fluorophenyl)-1,3,2-oxazaborolidines, (27) 3-ethyl-2,2-bis(p-tolyl)-1,3,2-oxazaborolidines. Apart from structural studies in the solid state, the compounds were also characterized by means of multinuclear NMR spectroscopy (1H, 11B, 13C) as well as UV/vis and FTIR. The typical 11B resonances were found in the range of (4-10 ppm). A series of characteristic metrical parameters for the compounds in the solid state as well as typical NMR shifts for the chelate target molecules was established that allowed for the determination of the coordination induced shift. The carbon atom bonded to the oxygen atom shifted upfield, while the carbon atom bonded to the nitrogen atom shifted downfield. Factors mentioned in the literature that has an influence on the hydrolytic stability on the heterocyclic borinate motif have been taken into consideration and verified for the systems researched in this study. The substitution at the nitrogen atom with one ethyl group caused the greatest increases in the N→B bond length (27) 1.714 Å, due to the increase in the nitrogen Lewis basicity, making it the least hydrolytically stable, these include compounds (24-26). Furthermore, DFT calculations were performed by employing Becke’s three parameter hybrid exchange functional with Lee–Yang–Parr functional (B3LYP) method using the Gaussian 16 program package (Rev. B01) employing the basis set 6-311++G(d,p), to corroborate and correlate the experimental findings, which gave a general R-squared value of 0.9978 for calculated vs experimental 13C chemical shifts. Thermal properties are recorded for select compounds, indicating the ΔH and the melting points. , Thesis (PhD) -- Faculty of Science, School of Biomolecular and Chemical Sciences, 2021
- Full Text:
- Date Issued: 2021-12
- Authors: Manana, Pholani Sakhile
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10948/53869 , vital:46027
- Description: A series of core-functionalized borinic acids was synthesized from Grignard reagents and tributylborate and reacted with ethanolamine, amino acids, 2-pyridylmethanol as well as 2-(ethyl amino ethanol). Among the borinic acids synthesized were the ones bearing: para-(2, 15, 16, 22, 27)-methyl, (3, 20, 25)-chloro, (4, 23, 26)-fluoro, (5)-methoxy; meta-(7, 17)-methyl, (9)-fluoro; ortho-(6)-methyl, (8)-chloro, (10, 18, 19)-methoxy substituents on their respective aromatic systems. All compounds obtained by condensation of the borinic acids with the aforementioned nitrogen-containing substrates were characterized structurally by means of diffraction studies based on single crystals and found to constitute chelate esters/amides featuring covalent B-O and dative N→B bonds. The chelate compounds researched in this study could be classified into four families and represent the compounds: ethanol amine: (1) 2,2-diphenyl-1,3,2-oxazaborolidines, (2) 2,2-bis(p-tolyl)-1,3,2-oxazaborolidines, (3) 2,2-bis(p-chlorophenyl)-1,3,2-oxazaborolidines, (4) 2,2-bis(p-fluorophenyl)-1,3,2-oxazaborolidines, (5) 2,2-bis(p-methoxyphenyl)-1,3,2-oxazaborolidines, (6) 2,2-bis(o-tolyl)-1,3,2-oxazaborolidines, (7) 2,2-bis(m-tolyl)-1,3,2-oxazaborolidines, (8) 2,2-bis(o-chlorophenyl)-1,3,2-oxazaborolidines, (9) 2,2-bis(m-fluorophenyl)-1,3,2-oxazaborolidines, (10) 2,2-bis(o-methoxyphenyl)-1,3,2-oxazaborolidines. α-amino acids : (14) 4-methyl-2,2-diphenyl-1,3,2-oxazaborolidin-5-ones, (15) 2,2-bis(p-tolyl)-1,3,2-oxazaborolidin-5-ones, (16) 4-methyl-2,2-bis(p-tolyl)-1,3,2-oxazaborolidin-5-ones, (17) 4-isopropyl-2,2-bis(m-tolyl)-1,3,2-oxazaborolidin-5-ones, (18) 4-methyl-2,2-bis(o-methoxyphenyl)-1,3,2- oxazaborolidin-5-ones, (19) 4-acetamidyl-2,2-bis(o-methoxyphenyl)-1,3,2- oxazaborolidin-5-ones, (20) 4-phenylethane-2,2-bis(p-chlorophenyl)-1,3,2 oxazaborolidin-5-ones. 2-pyridylmethanol: (21) 1,3-hydroxypyridyl-2,2-diphenyl 1,3,2-oxazaborolidines, (22) 1,3-hydroxypyridyl-2,2-bis(p-tolyl)-1,3,2-oxazaborolidines, (23) 1,3-hydroxypyridyl-2,2-bis(p-fluorophenyl)-1,3,2-oxazaborolidines 2-(ethyl amino ethanol): (24) 3-ethyl-2,2-diphenyl-1,3,2-oxazaborolidines, (25) 3-ethyl-2,2-bis(p-chlorophenyl)-1,3,2-oxazaborolidines, (26) 3-ethyl-2,2-bis(p-fluorophenyl)-1,3,2-oxazaborolidines, (27) 3-ethyl-2,2-bis(p-tolyl)-1,3,2-oxazaborolidines. Apart from structural studies in the solid state, the compounds were also characterized by means of multinuclear NMR spectroscopy (1H, 11B, 13C) as well as UV/vis and FTIR. The typical 11B resonances were found in the range of (4-10 ppm). A series of characteristic metrical parameters for the compounds in the solid state as well as typical NMR shifts for the chelate target molecules was established that allowed for the determination of the coordination induced shift. The carbon atom bonded to the oxygen atom shifted upfield, while the carbon atom bonded to the nitrogen atom shifted downfield. Factors mentioned in the literature that has an influence on the hydrolytic stability on the heterocyclic borinate motif have been taken into consideration and verified for the systems researched in this study. The substitution at the nitrogen atom with one ethyl group caused the greatest increases in the N→B bond length (27) 1.714 Å, due to the increase in the nitrogen Lewis basicity, making it the least hydrolytically stable, these include compounds (24-26). Furthermore, DFT calculations were performed by employing Becke’s three parameter hybrid exchange functional with Lee–Yang–Parr functional (B3LYP) method using the Gaussian 16 program package (Rev. B01) employing the basis set 6-311++G(d,p), to corroborate and correlate the experimental findings, which gave a general R-squared value of 0.9978 for calculated vs experimental 13C chemical shifts. Thermal properties are recorded for select compounds, indicating the ΔH and the melting points. , Thesis (PhD) -- Faculty of Science, School of Biomolecular and Chemical Sciences, 2021
- Full Text:
- Date Issued: 2021-12
The use of ambient seismic noise to investigate internal changes in a tailings storage facility and to image the subsurface geology in the Cradock area of the Eastern Cape
- Authors: Kunjwa, Thulisile
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/53642 , vital:45690
- Description: Passive seismic interferometry is a process by which ambient noise data recorded at different seismic stations can be cross-correlated to estimate Green's functions. In the past, both surface waves and body waves have successfully been extracted by cross-correlation of ambient noise data on both regional and global scales. Recent advancements in ambient seismic noise techniques have the potential to provide new methods for subsurface imaging and monitoring. The ambient noise data processing procedure divides into four principal phases: (1) single station data preparation, (2) cross-correlation and temporal stacking, (3) measurement of dispersion curves and (4) inversion of dispersion curves to obtain 1-D shear wave profiles and computation of 2-D shear wave velocity cross-section. The purpose of this study is to investigate whether ambient seismic noise can be used to image and detect internal changes within a mine tailings dam wall and to image the subsurface geology of part of the Eastern Cape Karoo near Cradock. In the first experiment, the investigation consisted of continuous ambient noise data recordings over a period of 3 days with 20 three-component short period geophones. The geophones were deployed over a survey wall of roughly 100 m in length at the Harmony Gold mine tailings dam in Welkom. In the second experiment, the investigation consisted of data recordings over a period of 35 days. The geophones were deployed in Cradock. The first phase of the data processing procedure included de-trending, de-meaning and band-pass filtering the data. This was done to ensure that any long period trends associated with instrument glitches are removed from the data. A spectrogram was then computed to view the spectrum of frequencies in the signal and to check if the filter that was designed was able to cut off the unwanted frequencies. The horizontal and vertical components of the ambient noise data were cross-correlated and picked between sensor pairs to create surface wave dispersion curves. Subsequently, the dispersion curves were inverted to estimate the shear wave velocity of the dam wall and subsurface as a function of depth. The computed cross sections of shear wave velocity indicated a low-velocity zone between 2 and 10 m below the surface on the dam wall, this suggested that the phreatic surface is much closer to surface in this area. In the second experiment, the interpolated shear wave velocity profiles indicated that there is a layer of low velocity zone between depths 250 to 300 m below the surface. The cross-correlations were also used to compute group velocity maps from periods 1.5 seconds to 30 seconds. The group velocity maps showed various high and low velocity anomalies. The high velocity zones observed on the eastern section of the map were interpreted as evidence of dolerite intrusions. The low velocity zones observed in the western and southern sections of the map interpreted as Karoo sediments that belong to the Adelaide Subgroup which is dominated by mudstones. , Thesis (MSc) -- Faculty of Science, Department of Geosciences (Geology and Geography), 2021
- Full Text:
- Date Issued: 2021-12
- Authors: Kunjwa, Thulisile
- Date: 2021-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/53642 , vital:45690
- Description: Passive seismic interferometry is a process by which ambient noise data recorded at different seismic stations can be cross-correlated to estimate Green's functions. In the past, both surface waves and body waves have successfully been extracted by cross-correlation of ambient noise data on both regional and global scales. Recent advancements in ambient seismic noise techniques have the potential to provide new methods for subsurface imaging and monitoring. The ambient noise data processing procedure divides into four principal phases: (1) single station data preparation, (2) cross-correlation and temporal stacking, (3) measurement of dispersion curves and (4) inversion of dispersion curves to obtain 1-D shear wave profiles and computation of 2-D shear wave velocity cross-section. The purpose of this study is to investigate whether ambient seismic noise can be used to image and detect internal changes within a mine tailings dam wall and to image the subsurface geology of part of the Eastern Cape Karoo near Cradock. In the first experiment, the investigation consisted of continuous ambient noise data recordings over a period of 3 days with 20 three-component short period geophones. The geophones were deployed over a survey wall of roughly 100 m in length at the Harmony Gold mine tailings dam in Welkom. In the second experiment, the investigation consisted of data recordings over a period of 35 days. The geophones were deployed in Cradock. The first phase of the data processing procedure included de-trending, de-meaning and band-pass filtering the data. This was done to ensure that any long period trends associated with instrument glitches are removed from the data. A spectrogram was then computed to view the spectrum of frequencies in the signal and to check if the filter that was designed was able to cut off the unwanted frequencies. The horizontal and vertical components of the ambient noise data were cross-correlated and picked between sensor pairs to create surface wave dispersion curves. Subsequently, the dispersion curves were inverted to estimate the shear wave velocity of the dam wall and subsurface as a function of depth. The computed cross sections of shear wave velocity indicated a low-velocity zone between 2 and 10 m below the surface on the dam wall, this suggested that the phreatic surface is much closer to surface in this area. In the second experiment, the interpolated shear wave velocity profiles indicated that there is a layer of low velocity zone between depths 250 to 300 m below the surface. The cross-correlations were also used to compute group velocity maps from periods 1.5 seconds to 30 seconds. The group velocity maps showed various high and low velocity anomalies. The high velocity zones observed on the eastern section of the map were interpreted as evidence of dolerite intrusions. The low velocity zones observed in the western and southern sections of the map interpreted as Karoo sediments that belong to the Adelaide Subgroup which is dominated by mudstones. , Thesis (MSc) -- Faculty of Science, Department of Geosciences (Geology and Geography), 2021
- Full Text:
- Date Issued: 2021-12